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  • Articles: DFG German National Licenses  (2)
  • 1995-1999  (2)
  • 1997  (2)
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  • Articles: DFG German National Licenses  (2)
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  • 1995-1999  (2)
Year
  • 1
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Temperature-programmed desorption (TPD) and electron spin resonance (ESR) techniques have been employed to investigate the oxygen adsorbed on the paramagnetic defect centers in dehydroxylated AlPO4-20, AlPO4-11, AlPO4-5, and VPI-5 molecular sieves. Two different adsorption sites are observed for the small-pore AlPO4-20, where oxygen is entrapped within the intracrystalline voids generated during the calcination step, as well as within the β-cages. However, the unidimensional molecular sieves AlPO4-11, AlPO4-5, and VPI-5 have only one type of adsorption site within their inner pores. The apparent activation energies of desorption (12.0-21.7 kcal mol-1) determined from the oxygen TPD results demonstrate that, as the pore size of the AlPO4 molecular sieve is larger, the interaction between the adsorbed oxygen and the molecular sieve framework becomes weaker.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The metal oxides MgO, BaO, Al2O3, SiO2, MgO–Al2O3, CaO–Al2O3, SrO–Al2O3, BaO–Al2O3 and MgO–SiO2 have been coated onto ribbons of the Fe-based amorphous alloy Metglas 2605S3A using a sol–gel process. The effects of the surface coating on the magnetic properties of the alloy are investigated. The d.c. hysteresis loop for ribbons coated with MgO and MgO–Al2O3 is more square shaped than that for the uncoated ribbon. For ribbons coated with BaO, SrO–Al2O3 and BaO–Al2O3 it is more inclined than for the uncoated ribbon. Significant differences in the frequency dependence of the effective permeability are observed that depend on the nature of the coated oxides. The core loss is also affected by the coating. These results may be explained in terms of a stress induced by the coating and the modification of the domain structure via elastic and/or magnetoelastic interactions. It is thought from the magnetoelastic interactions that the MgO and MgO–Al2O3 coatings induce tensile stresses whilst those of BaO, SrO–Al2O3 and BaO–Al2O3 induce compressive stresses.
    Type of Medium: Electronic Resource
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