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Mononuclear Bis(diazadiene)ruthenium(0) Complexes and the Coupling of Butadiene to a Diazadiene System (1990)

Rosenberger, Volker ; Dieck, Heindirk Tom

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 83-85

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ISSN: 0009-2940

Keywords: Diazadienes/Carbon-carbon coupling/Ruthenium(0) complexes/Ethylene complexes ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Complexes (dad)2RuCl2 (1) (dad = diazadiene, RN = CR'- CR'=NR) are reduced to (dad)2Ru (2) which react with L = CO or ethylene to give (dad)2RuL (3,5). Reduction of 1b ( R' = H) with magnesium-butadiene or reaction of 2b with butadiene leads to a new type of C-C coupling of butadiene to one of the diazadiene ligands (6b). Addition of CO induces a rearrangement to 7b by a hydride shift.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19901230117

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