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  • Articles: DFG German National Licenses  (6)
  • 1990-1994  (6)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 270 (1992), S. 301-301 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 271 (1993), S. 460-468 
    ISSN: 1435-1536
    Keywords: Regenerated cellulose fibres ; swollen state ; crystallite orientation ; amorphous orientation ; fibrillar structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The conditioned and wet tensile strength resp. modulus of solvent-spun and viscose-type cellulose fibres was correlated with their crystallite and amorphous orientation factor. It was found that the extrapolation of these tensile properties to the maximum degree of orientation results in identical values of the tensile strength resp. modulus in the conditioned and water swollen state. Proportional to a decreasing orientation factor the loss of strength and modulus by swelling increases. Additionally, a positive correlation was found between the wet tensile strength resp. modulus and the intensity of the interference of the equatorial small-angle x-ray scattering measured in the swollen state. This interference is caused by the elementary fibrils. The intensity of this interference is a measure for the fibrillar character of the swollen fibre structure. The fibrillability of the fibres suspended in water correlates positively with the crystallite orientation factor.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 29 (1990), S. 170-171 
    ISSN: 1435-1528
    Keywords: Yield stress ; rolling ballviscometer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 185 (1991), S. 249-257 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Vier Proben von Poly(oxyethylen) gelöst in Wasser wurden rheologisch untersucht. Fließkurven für verschiedene Molmassen und Konzentrationen wurden erhalten. Aus den no -Werten wurden die Netzwerk-Segmente, das scheinbare Fadenelement und die Durchdringungshemmung ermittelt. Das Polymere bildet in Wasser Verhängungsnetzwerke mit behinderter Durchdringung.
    Notes: Four samples of poly(oxyethylene) dissolved in water have been studied rheologically. Flow curves have been obtained for different molecular mass and concentration. From no the mass of network strand, the apparent chain element and the penetration hindrance have been obtained. The polymer turns out to form in water entanglement network solutions with somewhat hindered penetration.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of the enzymatic hydrolysis of regenerated cellulose fibers before and after acid prehydrolysis has been investigated. This pretreatment changes the kinetics from a monophasic to a biphasic first order reaction. Prolonged acid prehydrolysis increases the proportion of the enzymatically easily hydrolyzable cellulose form. The kinetics were correlated with corresponding changes of the degree of polymerization, crystallinity and crystallite size.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 43 (1992), S. 307-312 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Auswertung der Langperioden und Kristallitlängen originaler sowie vorbehandelter, lösungsersponnener Cellulosefasern ergab, daß diese in Richtung der Faserachse zu ca. 90% aus kristalliner Cellulose bestehen. Bei hochnaßfesten Viskosefasern beträgt dieser Anteil nur 50-60%. Die Intensität der Langperiode der lösungsersponnenen Fasern ist niedriger als die der hochnaßfesten Viskosefasern entsprechend einer geringeren Differenz zwischen ihrem kristallinen und amorphen Orientierungsfaktor. Zwischen dieser Differenz und der Langperioden-Intensität besteht eine signifikante Korrelation.
    Notes: The evaluation of the long periods and crystallite lengths of original and pretreated solvent spun cellulose fibres revealed that they consist of about 90% crystalline cellulose in the direction of the fibre axis. In the case of high wet modulus viscose fibres this percentage is only 50-60%. The intensity of the long period of solvent spun fibres is lower than that of the high wet modulus viscose fibres corresponding to a smaller difference between their crystalline and amorphous orientation factors. There is existing a significant correlation between this difference and the intensity of the long period.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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