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  • Articles: DFG German National Licenses  (3)
  • 1985-1989  (3)
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  • Articles: DFG German National Licenses  (3)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 2120-2122 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The simple cubic perovskite (Rb,Ba)BiO3 can be grown at temperatures below 350 °C by molecular beam epitaxy using a rf plasma atomic oxygen source. Films with superconducting onsets in resistivity as high as 27 K are obtained without annealing. The epitaxy proceeds in the normal (100) orientation on {100} SrTiO3, despite a 10% lattice mismatch. (110) epitaxy and spotty reflection high-energy electron diffraction (RHEED) patterns are obtained on {100} MgO substrates, despite the good lattice match for (100) growth. Streaked and spotty RHEED patterns have been obtained on either substrate. Sticking coefficients for bismuth depend on the growth conditions, indicating that the epitaxy is partially controlled by desorption kinetics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have used x-ray photoemission spectroscopy to study the core level spectra of 200 A(ring) Bi-Sr-Ca-Cu oxide thin films, in the hope that the importance of the surface sensitivity of photoemission is minimized for these samples, whose thickness is only 6–7 unit cells. The samples were annealed in oxygen at temperatures ranging from 600 to 870 °C, over which temperature range the thin films are converted from an amorphous insulating phase to an ordered superconducting phase with Tc (R=0)=80 K. Regardless of the annealing temperature, the Cu 2p spectra of all films show satellite structure indicative of Cu2+ states. Even the spectrum of an as-deposited film has a satellite similar to those observed for the annealed films, including the superconducting film. The similarity of the satellite structure in the core level spectra for all films suggests that the Cu-O interactions, such as the Cu d-O p orbital charge transfer energies and the hopping integrals, remain similar when the oxides undergo the insulator-superconductor transition through high-temperature anneal. That is, the same local Cu-O interaction exists before and after the superconducting phase sets in. This implies that the Cu valence alone does not determine the properties of high Tc superconductors.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 802-804 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new technique using ion beams to produce patterned thin films of the high-temperature perovskite superconductor YBa2Cu3O7−x from spin-on metalorganic precursors is described. Spin-coated precursor films are irradiated through a stencil mask with 2.5 MeV He+ ions, developed in solvent to remove unexposed material, and the remaining patterns are pyrolyzed. Black films of YBa2Cu3O7−x with pattern dimensions on the millimeter scale exhibit orientation with the c axis perpendicular to the film after heat treatments of 990 °C for 3 min. The conductivity of a highly oriented, ∼0.4-μm-thick patterned film is characterized by onset of the superconducting transition at 84 K and zero resistivity at 68 K, similar to those of an unirradiated film given the same thermal treatment. Studies on the nature of the ion beam exposed material are discussed.
    Type of Medium: Electronic Resource
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