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  • Articles: DFG German National Licenses  (18)
  • Chemistry  (16)
  • Inorganic Chemistry  (8)
  • 34.80.D  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 16 (1990), S. 97-106 
    ISSN: 1434-6079
    Keywords: 34.80.D ; 32.80.H
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have measured the ratio of cross sections σ(KL 2,3)/σ(K) for neon for electron impact in the energy range ofE 0=1.5 ... 50 keV via the intensity ofKL 2,3−LLL 2,3 Auger satellite lines relative to the intensity ofKL 1 L 2,3 (3 P) diagram line. The experimental ratio decreases over the full range of energyE 0 which is contrary to an earlier result by Carlson et al. We have also measured the alignment ofKL 2,3 1 P and3 P states via the angular distribution of Auger satellite intensity for the energy rangeE 0=1.5 ... 4 keV, within experimental error we have found a zero alignment. The totalK Auger spectrum, measured forE 0=40 keV and at the magic angle of emission ϑ=54.7°, has been decomposed into its components by using appropriate line shapes distorted by postcollision interaction. Finally, we discussed whether the lines observed at the high-energy side ofKL 2,3−LLL 2,3 Auger satellite lines can be interpreted as structures caused by an angular momentum exchange in the postcollision interaction predicted by Niehaus and Zwakhals.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 31 (1994), S. 53-54 
    ISSN: 1434-6079
    Keywords: 34.80.D ; 32.80.H
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract From intensity of Auger transitions (1s2p)−1 1 P,3 P→2p −3 2 P,2 D+e A − relative to 1s −1 2 S→2p −2 1 D+e A − measured at ϑ=54 and 90° relative to the primary electron beam we have determined the alignment of double vacancy states (1s 2p)−1 1 P and3 P of neon for electron impact ionization for the impact energies 1.5, 2.0, 2.5 and 4.0 keV. ForE 0=1.5, 2.0 and 2.5 keV the alignment is compatible with zero with an upper limit of , forE 0=4.0 keV a small negative value was found.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 74 (1912), S. 297-309 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 201 (1931), S. 41-74 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Bioluminescence and Chemiluminescence 1 (1986), S. 47-51 
    ISSN: 0884-3996
    Keywords: ATP ; luciferin-luciferase ; bioluminescent assay ; HLA-typing ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: The amount of adenosine triphosphate (ATP) in human lymphocytes was determined using a technique based on light emission from a bioluminescent reaction with luciferin-luciferase. The amount of ATP changed when cells were incubated in the presence of specific HLA antisera and complement. For determination of intracellular ATP a modified method was applied, which was based on reduction of extracellular ATP by the addition of ATPase. The results of titration of an anti-human lymphocyte serum using the bioluminescence assay were in agreement with the results of fluorescence vitality staining. Bioluminescent HLA-determination in 57 cell samples each tested with 5 different antisera also gave good agreement (95.8%) with the conventional method. From these experimental data the calculated ATP content per lymphocyte was 0.135 ± 0.058 pg ATP.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 49 (1977), S. 42-42 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 34 (1983), S. 764-764 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 43 (1961), S. 98-105 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Several cyclic diurethanes were synthesized by two different methods applying RUGGLIZIEGLER'S principle of dilution. Only by preparation from diamines and diol-bis-chlorocarbonate good yields could be obtained. Using diols and diisocyanates as starting materials linear polyurethans were the main products.
    Notes: Mehrere Cyclodiurethane wurden unter Anwendung des RUGGLI-ZIEGLERschen Verdünnungsprinzips nach zwei verschiedenen Verfahren synthetisiert. Bei der Darstellung aus Diaminen und Diol-bis-chlorkohlensäureestern konnten die Verbindungen in guten Ausbeuten gewonnen werden. Dagegen werden bei Anwendung von Diolen und Diisocyanaten als Ausgangsmaterialien im wesentlichen lineare Polyurethane erhalten.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 57 (1962), S. 241-254 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The bis-chlorocarbonates of some oligo-ethylene glycols HO - (CH2CH2O)nH (n = 1-6) were reacted with hexamethylene diamine, m-toluylene diamine, p-phenylene diamine respectively to form the corresponding cyclic diurethanes. The dependency of the yield regarding the ringsize shows a maximum with 17 members in the ring. Also the catalyzed reaction of diisocyanates with diols was used for the preparation of cyclic urethanes.In the presence of di-n-butyltin-dilaurate exchange reactions were observed between hydroxyl-endgroups and urethane-groups as well as between urethane-groups.
    Notes: Die Bis-chlorkohlensäureester einiger Oligoäthylenglykole HO - (CH2CH2O)nH (n = 1-6) wurden mit Hexamethylendiamin, m-Toluylendiamin bzw. p-Phenylendiamin zu den entsprechenden Cyclodi-urethanen umgesetzt. Die Ausbeute in Abhängigkeit von der Ringgröße ergibt ein Maximum bei einer Ringgliederzahl von etwa 17. Ebenso wird die katalysierte Reaktion von Diisocyanaten mit Diolen zur Darstellung von Cyclo-urethanen benutzt.In Gegenwart von Di-n-butylzinndilaurat werden Austauschreaktionen sowohl zwischen Hydroxylendgruppen und Urethangruppen als auch zwischen Urethangruppen beobachtet.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1529-1534 
    ISSN: 0044-2313
    Keywords: Formation of NH4[Ge(NH3)F5] ; structure ; ammonolysis ; ir spectrum ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Ammonolysis Reaction of (NH4)2GeF6. Synthesis and Structure of NH4[Ge(NH3)F5](NH4)2GeF6 reacts with ammonia to yield NH4[Ge(NH3)F5] at 280°C. The reaction path was elucidated by in situ time and temperature resolved X-ray powder diffraction. NH4[Ge(NH3)F5] crystallizes isostructurally to NH4[Si(NH3)F5] in the tetragonal space group P4/n (No. 85) with lattice constants a = 619.41(1) pm and c = 724.70(1) pm. The germanium atom is coordinated by five fluorine atoms and the nitrogen atom of the ammonia molecule. The ammonium cation is located on the Wyckoff position (2 a) in P4/n. The crystal structure is stabilized by extensive hydrogen bonding.
    Notes: (NH4)2GeF6 reagiert mit Ammoniak bei 280°C zu NH4[Ge(NH3)F5]. Der Reaktionsverlauf wurde in situ mit Hilfe der zeit- und temperaturaufgelösten Röntgenpulverdiffraktometrie verfolgt. Das so dargestellte NH4[Ge(NH3)F5] kristallisiert isostrukturell mit NH4[Si(NH3)F5] in der tetragonalen Raumgruppe P4/n (Nr. 85) mit den Gitterkonstanten a = 619,41(1) pm und c = 724,70(1) pm. Dabei ist das Germaniumatom verzerrt oktaedrisch von fünf Fluoratomen und dem Stickstoffatom des Ammoniakmoleküls koordiniert. Das Ammoniumion liegt auf der Tetraederpunktlage (2 a) in P4/n. Die Verbindung wird durch Wasserstoffbrückenbindungen stabilisiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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