Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
98 (1993), S. 231-235
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Time-of-flight mass spectrometry is used to investigate (TiN)n+ clusters produced by a laser-induced plasma reactor source. The mass spectral abundance patterns indicate that the clusters have cubic structures resembling subunits of the fcc lattice of solid TiN. The primary stoichiometries observed are (TiN)n+ (n=1–126), except for TinNn−1+ (n=14, 63). The most stable structures of the clusters are cuboids, in some cases containing a completed terrace. Even at the very early stages of crystal growth, the gas-phase clusters prefer a cubic crystalline atomic arrangement with a highly symmetric structure.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.464669
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