ISSN:
0935-6304
Keywords:
Enantioselective GC of chlorinated bis(propyl) ethers
;
environmental analysis
;
contamination of the Elbe River
;
cyclodextrin derivatives
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
---Cyclodextrin derivatives are evaluated as chiral stationary phases for the enantiomer separation of chlorinated bis(propyl) ethers (BPE). The enantiomeric composition of the 2,3,2′,3′- and 1,3,2′,3′-isomers of tetrachlorobis(propyl) ether in the Elbe River has been quantitatively determined by enantioselective gas chromatography and coupled gas chromatography/mass spectrometry in selected-ion-monitoring mode. Significant enantiomeric discriminations are observed in selected water samples, indicating that enantioselective bio-degradation mechanisms are at least partly responsible for the overall degradation processes.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
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