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  • Electronic Resource  (5)
  • 1995-1999  (5)
  • Chemistry  (3)
  • aluminosilicate gel  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 9 (1997), S. 169-181 
    ISSN: 1573-4846
    Keywords: aluminosilicate gel ; non-linear absorption ; metalloporphyrin ; spirooxazine ; time-resolved spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS),and1, 3-dihydro-1,3,3-trimethylspiro[2H-indole-2, 3′-[3H]-naphth[2,1-b][1,4]oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts.Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 9 (1997), S. 169-181 
    ISSN: 1573-4846
    Keywords: aluminosilicate gel ; non-linear absorption ; metalloporphyrin ; spirooxazine ; time-resolved spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS), and 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3′-[3H]-naphth[2,1-b][1,4]oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts. Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2112-2117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mechanistic model, which incorporates recent findings on the fluid dynamics in the riser of the circulating fluidized bed (CFB), is developed for predicting the suspension-to-wall heat-transfer coefficient in the riser. It is assumed that heat transfer between the gas-particle suspension and the riser wall takes place by the contact of both particle packets and an emulsion phase on the wall. A characteristic length (L), that is, a sliding distance of the emulsion phase along the heat-transfer surface, is introduced in the model, enabling the effect of the length of heat-transfer surface to be evaluated. It is found that the heat-transfer coefficient decreases with increasing L, but becomes increasingly insensitive to L when L is larger than 1 m. Agreement between model prediction and measurement is encouraging over a range of operating conditions, heat-transfer surface length, and riser diameters.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 36 (1997), S. 516-521 
    ISSN: 0021-9304
    Keywords: porous-coated ; titanium ; PLA-PGA ; protein release ; degradation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Tissue ingrowth into porous-coated orthopedic and dental implants is commonly used as a means to achieve long-term fixation of these prostheses. However, the degree of tissue ingrowth is often inadequate and inconsistent. If the pores of these implants are impregnated with a controlled drug release system delivering relevant growth factors, then it might be possible to stimulate more tissue ingrowth. The present study introduces such a system based on biodegradable polymers and investigates its protein release profile and polymer degradation characteristics. Porous coated titanium implants were impregnated with a mixture of a 50%-50% polylactic acid-polyglycolic acid copolymer and a model protein, soybean trypsin inhibitor. Control implants contained only the polymer and no protein. The implants were subjected to hydrolytic degradation in phosphate buffered saline at 37°C for periods of 3, 6, and 11 weeks. The protein release and the mass and molecular weight of the polymer were monitored. The results indicate that the protein is released in three distinct phases and the polymer loses almost all its mass and molecular weight by 11 weeks. There was a significant difference in the polymer degradation characteristics between the control and test implants, which might be the result of some complex polymer-protein interactions. © 1997 John Wiley & Sons, Inc. J Biomed Mater Res, 36, 516-521, 1997.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1040-0397
    Keywords: XPS analysis ; Fluoride ; Ion selective electrode ; Surface analysis ; Hydroxide interference ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Lanthanum fluoride and cerium fluoride single crystals, used as the sensing membranes of the fluoride ion-selective electrode (F-ISE), were investigated for their hydroxide interference and surface reactions with OH- in high pH conditions. While these membranes show fast response and excellent Nernstian behavior over a wide concertration range in buffered F- solutions, they deviate from the theoretical slope at high pH. CeF3, in particular, exhibits a much larger deviation from the Nernstian slope and a substantially slower response to a F- activity change compared to LaF3. This larger deviation is due to more extensive and faster formation of hydroxo-complexes, with the release of a greater amount of the fluoride ion into the hydrated gel layer. The slower response of the CeF3 membrane after contact with OH- is due to the formation of CeIV oxide on the surface, which acts as a blocking layer to the exchange of F-.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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