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  • Electronic Resource  (5)
  • 1990-1994  (5)
  • 1965-1969
  • 27.80.+w  (2)
  • Chemistry  (2)
  • 07.80  (1)
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  • Electronic Resource  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 350 (1994), S. 207-214 
    ISSN: 1434-601X
    Keywords: 27.80.+w
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Excited states in198,199Po have been studied by in-beamγ-ray spectroscopy. These nuclei were produced in the 4n and 5n reaction channels for 115 MeV20Ne on183W-targets. Multipolarities and mixing ratios ofγ-transitions were determined from DCO-ratios, leading to spin/parity assignments. In198Po,γ-cascades have been observed above several excited levels that are similar to the vibration-like structure built on the ground state. In199Po, the coupling of the oddi13/2 neutron seems to favor the spherical shape of the even core; no levels resembling the intruder states of the even nuclei are found. A semi-quantitative evaluation of the cross-sections for nuclei produced in fission and multi-particle transfer is presented.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0649
    Keywords: 07.77 ; 07.80 ; 32.80 F ; 14.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report here on the development of a high-temperature laser ion source useful for trace analysis and other applications. It consists of a high temperature ionization chamber, three tunable dye lasers pumped by copper vapor lasers for stepwise resonant ionization and a Mattauch-Herzog mass spectrometer for the analysis of photo-ions. The principle of the laser ion source and its theoretical efficiency are discussed, where the efficiency of a laser ion source is the ratio of photo-ions extracted out to the number of atoms introduced into the cavity. Experimentally, an efficiency of 2×10−3 has been achieved for technetium. The scheme of gated detection is described which is used for suppressing isobaric background of molybdenum. The possible improvements are briefly mentioned for achieving isotopic analysis of 108 atoms of 97,98Tc in the presence of 1015 atoms of molybdenum, as separated chemically from molybdenum ore. Such an analysis of technetium isotopes produced in molybdenite ore by a (v,e −) reaction, is expected to yield information about the solar neutrino flux.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Keywords: 21.10.−k ; 23.20.Ck ; 27.80.+w
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The level structure of196Po has been studied using a160Dy(40Ar, 4n) reaction and a recoil-catcher technique to reduce fission. The results showed a sharp drop off in the first (2+) and (4+) energies relative to systematics implying an abrupt increase in the quadrupole collectivity at N=112. In addition, second (2+) and(4+) states were identified at 859 and 1388 keV, respectively, suggesting the discovery of a 4p2h deformed band in Po isotopes which is related to known 2p2h proton bands in several Pb isotopes. A prompt183W(20Ne, 5n@#@) experiment located similar second 2+ and 4+ states at 1039 and 1483 keV in198Po providing corroboration and extended information on the properties of the new Po deformed bands. A measured halflife of 850 (90) ns for the 2491 keV (11−) state in196Po implied collective E3 contributions to the extractedB (@#@ E3; 11−→8+)=27(5) W.u.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The collision-induced dissociation of positively charged gold clusters (2-23 atoms) stored in a Penning trap has been studied. After collisions with rare gases, excited clusters predominantly decay by emission of one or two atoms. The loss of two atoms occurs most probably through the emission of a dimer rather than by a sequential evaporation. The minimum kinetic energies of clusters required to induce dissociation exhibit a pronounced odd-even effect. Clusters with an even number of delocalized electrons are more stable than those with an odd number.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 133-136 
    ISSN: 0749-1581
    Keywords: 17β-Substituted 14α-steroids ; 7α-substituted 14α-steroids ; 1H NMR ; 13C NMR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: γgaucheEffects of 17β- and 7α-substituted 14α-steroids were studied by 1H and 13C NMR spectroscopy. A linear correlation was found between the 1H chemical shift of H-12β and the 13C chemical shift of C-12 for C-17β-substituted steroids and between the chemical shifts of H-14α and C-14 in C-7α-substituted compounds.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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