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  • Electronic Resource  (2)
  • 1990-1994  (2)
  • 17β-Substituted 14α-steroids  (1)
  • 35.10.Fk
Material
  • Electronic Resource  (2)
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Year
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  • 1
    ISSN: 1434-6079
    Keywords: 31.30.Gs ; 31.50. + w ; 35.10.Fk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The hyperfine spectra of the 5s4d 3 D 1-5s20f, 5s4d 3 D 2-5s23f, and 5s 4d 3 D 3-5s32f transitions of87Sr (I=9/2) have been measured by collinear fast beam laser spectroscopy. The structure in the upper configurations is highly perturbed by fine structure splitting that is of comparable size to the hyperfine interaction energy. These perturbations can be adequately treated with conventional matrix diagonalization methods, using the 5s-electron magnetic dipole interaction terma 5s and the unperturbed fine structure splittings as input parameters. Additionally, hyperfine constants for the lower 5s4d 3 D configurations, including theA- andB-factors and a separation of the individuals- andd-electron contributions to these factors, are derived.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 133-136 
    ISSN: 0749-1581
    Keywords: 17β-Substituted 14α-steroids ; 7α-substituted 14α-steroids ; 1H NMR ; 13C NMR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: γgaucheEffects of 17β- and 7α-substituted 14α-steroids were studied by 1H and 13C NMR spectroscopy. A linear correlation was found between the 1H chemical shift of H-12β and the 13C chemical shift of C-12 for C-17β-substituted steroids and between the chemical shifts of H-14α and C-14 in C-7α-substituted compounds.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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