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  • 1990-1994  (9)
  • Chemistry  (6)
  • Engineering  (3)
  • Chemical Engineering
  • Control of breathing
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Year
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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 1317-1322 
    ISSN: 0887-624X
    Keywords: pseudo IPNs ; NR ; PCU ; conducting polymers ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Recent DC conductivity measurements on iodine-doped full and psuedo IPNs of poly (carbonate-urethane) (PCU) and natural rubber (NR) reveal that these materials possess a modest conductivity. Both such full and pseudo IPNs (with linear NR chains) are single-phased materials if the NR is of sufficiently high molecular weight derived from Brazilian Manihot glaziovii. On iodine doping the electrical conductivity rises eight orders of magnitude of both the full IPN (to ca. 10-5S cm-1) and the pseudo IPN (to ca. 10-4 S cm-1). A simple theory based on the assumption that conduction occurs essentially along the linear NR chains, composing a percolation cluster, in the iodine-doped pseudo IPNs of PCU and NR accounts for the observed electrical conductivity dependence on temperature, iodine molality, and weight fraction of NR. As temperature decreases the DC conductivity falls and the material becomes essentially an insulator. At sufficiently low temperature (ca. 115 K) this trend reverses and the DC conductivity rises by two orders of magnitude with further decreasing temperature up to that of liquid helium. © 1994 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2395-2400 
    ISSN: 0887-624X
    Keywords: pseudo IPNs ; PCU ; CR ; conducting polymer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A number of pseudo IPNs of poly(carbonate-urethane) (PCU) and crosslinked polychloroprene (CR) have been synthesized and characterized. The single phase morphology of these novel pseudo IPNs has been confirmed by DSC measurements and electron microscopy. The room temperature electrical conductives of homopolymers and pseudo IPNs have been investigated for both undoped and iodine-doped samples. © 1994 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Numerical Linear Algebra with Applications 1 (1994), S. 313-329 
    ISSN: 1070-5325
    Keywords: Discretization method ; Nonlinear ABS class ; Newton-type method ; Quadratic convergence ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics
    Notes: In this paper we give a class of algorithms for solving nonlinear algebraic equations using difference approximations of derivatives. The class is a modification of the original ABS class with the advantage of requiring less function evaluations. Special cases include the methods of Brown and Brent and the discretized Newton method, which is formulated in a way requiring fewer function evaluations per iteration.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1695-1701 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A variety of polyorganosiloxanes containing dimethyl, diphenyl, and methylphenyl substituents were studied to determine transparency and optical radiation hardness. Siloxanes show superior optical radiation hardness when compared to optical thermoplastics such as PMMA. Transparency is diminished in polymers containing diphenyl units. This is attributed to the inability to remove traces of the crystalline monomer. Methylphenyl polymers are highly transparent. The maximum attainable refractive index in transparent systems is 1.53.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2055-2057 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 1429-1437 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The crystal orientation distribution in injection-molded bars made from several polypropylene compounds has been investigated using pole figure analysis. The fillers used were glass fibers, chalk, and talc, and some compounds contained one filler and others contained glass fibers plus one or both of the others. All compounds showed strong orientation in the skin with the b-axis of the monoclinic crystals lying preferentially normal to the flow direction and in many cases parallel to the normal to the bar face. This normal direction orientation was very strong in compounds containing talc and is probably caused by crystals forming with their (010) planes on the talc platelet faces, which align themselves parallel to the mold face. Strong orientation persists into the interior of the moldings containing talc, whereas in the other compounds, the orientation at intermediate depths is much less pronounced than in the skin. © 1992 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 15 (1991), S. 735-752 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A direct boundary element method for the iterative analysis of the lowered groundwater level and the steady-state airflow in porous soil for tunnels driven under compressed air is presented. The soil may be zoned and anisotropic. It is shown that disregard of the compressibility of the air leads to results for the excess air pressure and the flow of air through the surface of the soil, which are on the unsafe side. The lowered groundwater level is determined by means of an iterative procedure. During the iteration large changes of the shapes of boundary elements may occur. In order to reduce the resulting danger of divergence of the iteration, the boundary element mesh is adapted suitably in the course of the iteration process.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 19 (1994), S. 981-995 
    ISSN: 0271-2091
    Keywords: Pressure-based method ; All-speed ; Blast wave ; Two-phase flow ; Combustion instability ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An improved pressure-based method has been applied to predict the two-dimensional instability analysis of liquid-fuelled rocket engines. This method is non-iterative for transient flow calculations and applicable to all-speed flows. Validation cases include the shock-tube problem, the blast flow field and unsteady spraycombusting flows. Computations for the combustion instability analysis were carried out for various combustion parameters such as spray initial conditions and combustor geometries. Unsteady behaviours of the stable and unstable spray flame fields and effects of acoustic oscillations on the fuel droplet vaporization and combustion process are studied in detail. The present numerical model successfully demonstrates the capability of predicting combustion instability as well as fast transient compressible flows at all speeds.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 24 (1993), S. 173-178 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The trisodium salt of 2-(4-sulphophenylazo)-1,8-dihydroxynaphthalene-3,6-disulphonic acid (SPADNS) was studied by Raman and surface-enhanced Raman spectroscopy (SERS) techniques. The Raman spectra of SPADNS powder and aqueous solution were investigated and an assignment of the Raman bands was made taking into account its infrared absorpiton spectrum. SPADNS tatomers, o-hydroxyazo and o-quinone hydrazone, are also discussed. Although the assignment is still preliminary owing to the complex structure of the SPADNS molecule, it provides useful information for SERS investigations of SPADNS in aqueous silver sol and on silve film. The results of SERS are compared with those of visible absorption spectra and x-ray photoelectron spectra (XPS) and the adsorption configuration of the SPADNS molecule on a silver surface is considered.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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