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  • Electronic Resource  (2)
  • 1985-1989  (2)
  • 33.70.−w  (1)
  • 42.60  (1)
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  • Electronic Resource  (2)
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  • 1985-1989  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    A simple model for the velocity modulation detection technique of molecular ions (1989)
    Springer
    Applied physics 48 (1989), S. 235-242 
    Details
    ISSN: 1432-0649
    Keywords: 35.80.+s ; 33.70.−w
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present a simple model to describe the line-profile of velocity modulated ions. This model is based on Langevin's theory of the mobility and on the independence of the electric field strength on the discharge current in the ideal positive column. A comparison of time constants responsible for the drift of the ions, the concentration, and the ignition and extinction of the discharge itself is essential for a rough understanding of the velocity modulation. The behaviour of H3O+ ions in an ac glow discharge was examined. Under our experimental conditions the line-profile can be explained by a temporal dependence of the velocity which is close to a square-wave. Due to this particular temporal dependence the amplitude of the signal only depends on the concentration modulation, while the line-shape is a simple difference line-profile.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00694351
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Computer controlled diode laser spectrometer with a helium evaporation cryostat and spectroscopy of thev 3 vibration of NCO (1989)
    Springer
    Applied physics 48 (1989), S. 105-110 
    Details
    ISSN: 1432-0649
    Keywords: 42.60 ; 33.20
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A computer-controlled diode laser spectrometer for the 1200 to 2500 cm−1 spectral region is described. The spectrometer has been applied to high resolution spectroscopy of the NCO radical at 5.2 μm. The lead-salt diode lasers are cooled to their operating temperature with a temperature adjustable helium evaporation cryostat. Computer-controlled tuning procedures for the frequency tuning of the diode lasers have been developed; they are independent of tables describing the tuning characteristics of the diode lasers. 41 lines of the antisymmetric stretching-vibrationv 3 of the linear NCO radical have been observed. We were able to detect vibration-rotation transitions in both2 π 1/2 and2 π 3/2 fine structure sublevels. These measurements led to the precise determination of additional molecular constants.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00692134
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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