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  • Electronic Resource  (2)
  • 1985-1989  (2)
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  • Electronic Resource  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 38 (1985), S. 57-64 
    ISSN: 1432-0649
    Keywords: 06 ; 32
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new laser approach for the isotopically selective analysis of noble gases is presented. This approach uses noble gas atoms prepared in the 1s 5 metastable state. Hyperfine levels in the 1s 5 and 2p 9 states form two-level systems in Ne, Ar, Kr, and Xe which can be excited by a commercially available single-frequency laser system. Absorption of photons from such a laser, and the resulting momentum transfer, can be used to selectively deflect the desired isotope from a supersonic atomic beam into a detection area. Light from the same laser can then be used to selectively count atoms of the desired isotope using the photon-burst technique. Thus, enrichment and selective detection are accomplished with a single laser in a single pass through the apparatus. The problem of analyzing for85Kr in a sample of noble gases extracted from the air is examined in detail. This is a stringent test of the selectivity of this approach because85Kr has the same nuclear spin, and thus similar hyperfine splittings, as naturally occurring83Kr. Calculations indicate that isotopic selectivity of the new approach is easily adequate to resolve85Kr in a 1010 excess of83Kr.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 47 (1988), S. 201-206 
    ISSN: 1432-0649
    Keywords: 32.70.Jz ; 35.10.Fk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have investigated several effects of optical pumping in the hyperfine spectrum of the6s6p 1 P 1⇔6s 2 1 S 0 transition in137Ba. Most of these effects are explained by absorption strength changes which occur because of redistribution of population among magnetic substates. At very low laser intensities, no redistribution effects are observed. At higher intensities, it is possible to either empty the magnetic substates that are accessible to optical excitation, or to redistribute the population among these states until a steady-state condition is achieved. The first case results in the familiar disappearance of a hyperfine line. The less familiar second case can result in peak-height ratios in the Ba1 P 1⇔1 S 0 hyperfine spectrum that differ by almost a factor of three from the low-intensity case. In this second case, the observed linewidth can either broaden or narrow, depending on whether redistribution decreases or increases absorption strength. At high intensities, saturation effects dominate and branching to intermediateD states becomes apparent. We report here the result of a numerically integrated rate equation model which shows good agreement with our experiments.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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