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  • Electronic Resource  (2)
  • 1980-1984  (2)
  • Ce(IV)-initiated polymerization  (1)
  • Extractants for available Zn  (1)
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  • Electronic Resource  (2)
Years
  • 1980-1984  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 261 (1983), S. 390-393 
    ISSN: 1435-1536
    Keywords: vinyl polymerization ; Ce(IV)-initiated polymerization ; polymerization by Ce(IV)-glucose redox system ; redox polymerization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Aqueous polymerization of acrylonitrile (M) initiated by the Ce(IV)-glucose (R) redox system has been studied under nitrogen in the temperature range of 30–40 °C. The rate of polymerization (Rp) is proportional to [M]2, [R] and inversely proportional to [Ce(IV)]. The rate of ceric ion disappearance is proportional to [R] and [Ce(IV)]. The end group in the polymer is characterised by IR spectra. A suitable kinetic scheme has been proposed and explained in the light of these experimental findings.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: Extractants for available Zn ; Hill and forest soils ; Rice ; Threshold value ; Zinc response
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The available Zn in 25 soils of Sub-Himalayan hill and forest region was determined by using some chemical extractants to evaluate its critical limit in soils and rice plant. The critical limit of soil available Zn using DTPA-CaCl2, DTPA-NH4HCO3, EDTA-NH4OAc and EDTA-(NH4)2CO3 was 0.76, 0.86, 0.85 and 1.18 ppm, respectively. The amount of Zn extracted by these extractants was positively and significantly correlated with per cent dry matter yield. In addition to per cent dry matter yield, the Zn extracted by DTPA-CaCl2, DTPA-NH4 HCO3 and EDTA-(NH4)2CO3 was also positively correlated with Zn concentration in 3rd leaf of rice, Zn concentration in rice shoots, Zn uptake by rice shoots and organic carbon content of the soil, and negatively correlated with soil pH.The 2N MgCl2 and 0.1N HCl extractants were found to be not suitable for these soils. Among the four promising extractants, EDTA-(NH4)2CO3 was most efficient as the value of critical limit determined by it expressed 82.4% predictability in the degree of accuracy against 36.8% with EDTA-NH4OAc. Hence EDTA-NH4OAc is the least efficient extractant for estimation of available Zn in such soils. The critical Zn concentration in 3rd leaf of rice was worked out to be 21.5 ppm below which economic responses to Zn application can be expected.
    Type of Medium: Electronic Resource
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