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  • Electronic Resource  (2)
  • 1980-1984  (2)
  • Polymer and Materials Science  (1)
  • entropy  (1)
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  • Electronic Resource  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 259 (1981), S. 1027-1030 
    ISSN: 1435-1536
    Keywords: Steric configurational ; entropy ; flocculation ; dispersions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary Theories are developed that predict the magnitude of the effects of particle configurational entropy on the flocculation behaviour of sterically stabilized dispersions. The free energy associated with the loss of configurational entropy on flocculation is relatively small (less than 10kT for the usual volume fractions studied) but may be responsible for the small dependence of the critical flocculation point on volume fraction of latex reported in some, but not all, experiments.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 3173-3179 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A theoretical procedure is developed that allows the importance of bimolecular termination in the aqueous phase of an emulsion polymerization to be determined. This shows that with sparinglysoluble and slowly propagating monomers like styrene, significant termination occurs in the aqueous phase at high initiator concentrations, as found experimentally. With more water soluble monomers, aqueous phase termination is likely to be small.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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