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  • Electronic Resource  (36)
  • Chemistry  (31)
  • Inorganic Chemistry  (7)
  • General Chemistry  (5)
  • enthalpy of crystallization  (5)
  • Acetone  (2)
Material
  • Electronic Resource  (36)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 1029-1039 
    ISSN: 1572-8927
    Keywords: Activity coefficients ; enthalpies of solution and hydration ; enthalpy of crystallization ; lithium nitrate ; lithium nitrate trihydrate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpies of crystallization of LiNO3 and LiNO3−3H2O from aqueous solutions at 25°C, measured by a calorimetric method and determined from the previously published data on the concentration dependence of the enthalpy of solution, are reported. The results are compared with the values obtained from the concentration dependences of the activity coefficients and from the temperature dependences of the solubilities. The enthalpy of solution at infinite dilution and the enthalpy of hydration are given.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 437-446 
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; lithium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpy of LiCl at 25°C in LiCl-H2O-cosolvent systems is determined calorimetrically as a function of the cosolvent content in the mixed solvent. This parameter is used for the investigation of heat phenomena accompanying the solvation of the salt in a saturated solution. The cosolvents employed include methanol, acetone, and N,N-dimethylformamide. The most pronounced change is effected by replacement of water with N,N-dimethylformamide.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 447-455 
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; magnesium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpies of MgCl2 in MgCl2−H2O-cosolvent systems at 25°C were determined calorimetrically as a function of the cosolvent content in the mixed solvent. Methanol, acetone, and N,N-dimethylformamide were employed as cosolvents. The results show the individual cosolvents to have very differently influences on the energy state of the salt in the saturated solution. The most pronounced changes are effected by an increase of the DMF content in the mixed solvent. The intensity of Mg2+-DMF interaction at a higher DMF content in the saturated solution considerably exceeds the Li+-DMF interaction in LiCl solutions.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 24 (1995), S. 659-669 
    ISSN: 1572-8927
    Keywords: Ammonium aluminum sulphate dodecahydrate ; enthalpies of solution ; enthalpy of crystallization ; solubility ; vapor pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Enthalpies of crystallization of NH4Al(SO4)2·12H2O from aqueous solutions at 25°C, measured using a calorimetric method and determined from previously published data on the concentration dependence of the enthalpy of solution, are reported. The results are compared with the values obtained from the temperature dependence of solubility and from vapor pressure data by using the Williamson equation. The integral and partial molar enthalpies of solution in concentrated and diluted solutions are given.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 15 (1986), S. 269-282 
    ISSN: 1572-8927
    Keywords: Activity coefficients ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of formation ; lithium chloride ; solubility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpies of crystallization of LiCl and LiCl·H2O from aqueous solutions at 25°C are reported as measured by a calorimetric method and derived from the previously published concentration dependence of the enthalpy of solution data. The results are compared with those obtained from the concentration dependence of activity coefficients and from the temperature dependence of solubilities.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 10 (1927), S. 815-819 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 11 (1928), S. 1228-1241 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 1885-1885 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 11 (1928), S. 172-179 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 518-524 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Custom-Tailored Coating-Interface Systems by Means of lon Beam Assisted DepositionA coated sample represents in its most simple form a threefold junction consisting of substrate interface and top layer. In many cases the top layer consists again of several sublayers or the interface contains a modified substrate surface and an interconnection between top layer and interface. An ideal coating technique is evaporation under simultaneous ion bombardment with an ion source it is possible because of several free parameters to come close to an ideal system.For the coating Al/Al2O3 on steel it is shown that the width of a composition gradient between the sublayers Al and Al2O3 can be optimized with respect to excellent corrosion resistance.The example CrxN coating on steel or corrosion and wear resistence demonstrate the ability to optimize the corrosion and wear resistence by modifying the microstructure via variation of the parameters ion energy, ion impact angle, ion to atom ratio and process temperature.Finally, TiN layers on steel were chosen to show that the ion beam parameters influence the porosity and the crystal structure of the coatings. This fact can be used to optimize the corrosion protection or wear reduction obtained by the coating. Especially the multilayer Ti/TiO2/TiN exhibits very interesting properties.
    Notes: Ein beschichtetes Bauteil stellt in seiner einfachsten Form einen Dreierverbund aus Substrat, Interface und Schicht dar, in vielen Fällen kann die Schicht aus mehreren Untersystemen bzw. das Interface aus der modifizierten Substatrandschicht und einem Zwischenbereich zur Schicht bestehen. Eine ideale Beschichtungsmethode sollte es daher erlauben, alle diese Schichten bzw. Schichtbereiche in kontrollierter und aufeinander abgestimmter Form zu erzeugen.Mittels des IBAd-Verfahrens, bei dem Aufdampfschichten während ihrer Abscheidung mit Ionen aus einer Ionenquelle beschossen werden, ist es möglich, infolge der zahlreichen frei wählbaren Parameter sich an das ideale System heranzutasten.Anhand des Verbunds Stahl/Al/Al2O3 wird erlätert, wie durch einen in der Ausdehnung optimierten Zusammensetzungsgradienten das Interface zwischen den Subschichten Al und Al2O3 bezüglich des Korrosionsschutzvermögens der Schicht verbessert werden kann.An CrxN-Schichten wird demonstriert, daß durch die Wahl der Parameter Ionenenergie, Ioneneinfallswinkel, Ionen/Atom-Verhältnis und Prozeßtemperatur über die Mikrostruktur von Schicht und Oberfläche das Verschleiß-und Korrosionsverhalten sowie die Härte angepaßt werden können.Am Beispiel TIN auf Stahl zeigt sich, daß je nach Ionenstrahlparameter die Porosität und damit das Korrosionsverhalten bzw. die Kristallinität und damit Härte und Verschleißverhalten optimiert werden können. Besonders Mehrlagenschichten Ti/TiO2/TiN zeigen interessante Eigenschaften.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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