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  • Electronic Resource  (33)
  • Chemistry  (31)
  • Inorganic Chemistry  (7)
  • General Chemistry  (5)
  • Acetone  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 437-446 
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; lithium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpy of LiCl at 25°C in LiCl-H2O-cosolvent systems is determined calorimetrically as a function of the cosolvent content in the mixed solvent. This parameter is used for the investigation of heat phenomena accompanying the solvation of the salt in a saturated solution. The cosolvents employed include methanol, acetone, and N,N-dimethylformamide. The most pronounced change is effected by replacement of water with N,N-dimethylformamide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 447-455 
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; magnesium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpies of MgCl2 in MgCl2−H2O-cosolvent systems at 25°C were determined calorimetrically as a function of the cosolvent content in the mixed solvent. Methanol, acetone, and N,N-dimethylformamide were employed as cosolvents. The results show the individual cosolvents to have very differently influences on the energy state of the salt in the saturated solution. The most pronounced changes are effected by an increase of the DMF content in the mixed solvent. The intensity of Mg2+-DMF interaction at a higher DMF content in the saturated solution considerably exceeds the Li+-DMF interaction in LiCl solutions.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 10 (1927), S. 815-819 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 11 (1928), S. 1228-1241 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 1885-1885 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 11 (1928), S. 172-179 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 518-524 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Custom-Tailored Coating-Interface Systems by Means of lon Beam Assisted DepositionA coated sample represents in its most simple form a threefold junction consisting of substrate interface and top layer. In many cases the top layer consists again of several sublayers or the interface contains a modified substrate surface and an interconnection between top layer and interface. An ideal coating technique is evaporation under simultaneous ion bombardment with an ion source it is possible because of several free parameters to come close to an ideal system.For the coating Al/Al2O3 on steel it is shown that the width of a composition gradient between the sublayers Al and Al2O3 can be optimized with respect to excellent corrosion resistance.The example CrxN coating on steel or corrosion and wear resistence demonstrate the ability to optimize the corrosion and wear resistence by modifying the microstructure via variation of the parameters ion energy, ion impact angle, ion to atom ratio and process temperature.Finally, TiN layers on steel were chosen to show that the ion beam parameters influence the porosity and the crystal structure of the coatings. This fact can be used to optimize the corrosion protection or wear reduction obtained by the coating. Especially the multilayer Ti/TiO2/TiN exhibits very interesting properties.
    Notes: Ein beschichtetes Bauteil stellt in seiner einfachsten Form einen Dreierverbund aus Substrat, Interface und Schicht dar, in vielen Fällen kann die Schicht aus mehreren Untersystemen bzw. das Interface aus der modifizierten Substatrandschicht und einem Zwischenbereich zur Schicht bestehen. Eine ideale Beschichtungsmethode sollte es daher erlauben, alle diese Schichten bzw. Schichtbereiche in kontrollierter und aufeinander abgestimmter Form zu erzeugen.Mittels des IBAd-Verfahrens, bei dem Aufdampfschichten während ihrer Abscheidung mit Ionen aus einer Ionenquelle beschossen werden, ist es möglich, infolge der zahlreichen frei wählbaren Parameter sich an das ideale System heranzutasten.Anhand des Verbunds Stahl/Al/Al2O3 wird erlätert, wie durch einen in der Ausdehnung optimierten Zusammensetzungsgradienten das Interface zwischen den Subschichten Al und Al2O3 bezüglich des Korrosionsschutzvermögens der Schicht verbessert werden kann.An CrxN-Schichten wird demonstriert, daß durch die Wahl der Parameter Ionenenergie, Ioneneinfallswinkel, Ionen/Atom-Verhältnis und Prozeßtemperatur über die Mikrostruktur von Schicht und Oberfläche das Verschleiß-und Korrosionsverhalten sowie die Härte angepaßt werden können.Am Beispiel TIN auf Stahl zeigt sich, daß je nach Ionenstrahlparameter die Porosität und damit das Korrosionsverhalten bzw. die Kristallinität und damit Härte und Verschleißverhalten optimiert werden können. Besonders Mehrlagenschichten Ti/TiO2/TiN zeigen interessante Eigenschaften.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 18 (1987), S. 356-359 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Surface engineering of light weight materials with ion- and plasma-assisted methodsIncreasing applications of light weight materials are expected in the future. Pursuing this trend surface engineering of these materials - especially ion- and plasma-assisted methods - swill be of increasing interest to enhance their wear and corrosion resistance. In a research co-operation some promising methods were examined on different aluminium and titanium alloys to assess their potential to increase the surface properties. Among these were magnetron sputtering of chromium nitride, ion beam assisted deposition of Cr/CrN and Al/A2O3 layers, ion implantation and ion beam assisted nitriding. Compared to the steel substrates the assessment of the mechanical properties such as the critical load of the scratch test of the coated light weight materials is different. Furthermore, it could be shown that both spherical section and glow discharge optical spectroscopy are useful methods to characterize the near-surface zone influenced by ion implantation.
    Notes: Es ist zu erwarten, daß die Anwendungsbreite von Leichtmetall-legierungen in Zukunft noch steigen wird. Mit diesem Trend werden auch oberflächentechnische Methoden - insbesondere ionen- und plasmaunterstützte Verfahren - gefragt sein, um den Verschleiß- und Korrosionswiderstand der Oberflächen zu verbessern. Im Rahmen eines Verbundprojektes wurden verschiedene aussichtsreiche Verfahren untersucht, um ihr Potential zur Verbesserung der Oberflächeneigenschaften von Aluminium- und Titanlegierungen einschätzen zu können. Hierunter befanden sich das Magnetronsputtern von Chromnitrid, die ionenstrahluntersützte Abscheidung von Cr/CrN- und Al/A2O3Schichten, die Ionenimplantation und das Ionenstrahlnitrieren. Im Vergleich mit beschichteten Stahlsubstraten ergeben sich Unterschiede bei der Einschätzung wichtiger mechanischer Eigenschaften, wie der im Ritztest ermittelten kritischen Last. Weiterhin konnte gezeigt werden daß sowohl der Kalottenschliff als auch die Glimmentladungspektroskopie gut geeignet sind, die durch Ionenimplantation beeinflußte Randzone zu charakterisieren.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 109-119 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Formation of Wear Resistant Surface Layers by Ion Beam TechniquesIon beam techniques are state of the art procedures for the microelectronic industries. Recently they found more and more interest in materials science with respect to surface improvement of polymers, ceramics and metals.In this contribution at first the procedures and the equipment for ion implantation and ion beam assisted deposition are described.Then examples for basic investigations concerning the formation of hard, dense and non-porous surface coatings with potential for wear and corrosion inhibition are given. Especially the interdependency of ion beam parameters, microstructure of coating and interface and macroscopic properties of the coating/substrate system are discussed. Finally the surface treatment of piston seals, ball bearings and metal forming tools is mentioned illustrating the application potential of ion beam techniques.
    Notes: Die in der Mikroelektronik industriell angewandten Ionenstrahlverfahren finden mehr und mehr Eingang in die Materialforschung zur Oberflächenvergütung von Polymeren, Keramiken und Metallen. In diesem Beitrag werden zunächst die Ionenimplantation und die ionenstrahlgestützte Beschichtung (IBAD) methodisch und apparativ beschrieben. Sodann werden Beispiele für Grundlagenuntersuehungen zur Erzeugung harter, dichter, verschleiß- und korrosionsmindernder Randschichten erwähnt. Dabei wird besonders anf die Zusammenhänge zwischen Ionenstrahlparametern, Mikrostruktur der Schicht bzw. Grenzzone Schicht/Substrat und mechanischen und chemischen makroskopischen Systemeigenschaften eingegangen. Schließlich werden am Beispiel von Kolbenringen, Umformwerkzeugen und Wälzlagern Anwendungspotentiale der Verfahren erläutert.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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