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  • Electronic Resource  (29)
  • Analytical Chemistry and Spectroscopy  (21)
  • Coleoptera  (4)
  • Physical Chemistry  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical ecology 20 (1994), S. 3207-3219 
    ISSN: 1573-1561
    Keywords: Aggregation pheromone ; triene ; tetraene ; hydrocarbon ; Coleoptera ; Nitidulidae ; Carpophilus davidsoni ; Australian sap beetle ; trapping
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract A male-produced aggregation pheromone was identified for the Australian sap beetle,Carpophilus davidsoni Dobson (Coleoptera: Nitidulidae), by bioassay-guided fractionation of volatiles collected from feeding beetles. The most abundant components were: (2E,4E,6E)-5-ethyl-3-methyl-2,4,6-nonatriene, (3E,5E,7E)-6-ethyl-4-methyl-3,5,7-decatriene, (2E,4E,6E,8E)-3,5,7-trimethyl-2,4,6,8-undecatetraene, and (2E,4E,6E,8E)-7-ethyl-3,5-dimethyl-2,4,6,8-undecatetraene. The relative abundance of these components in collections from individual males feeding on artificial diet was 100:7:9:31, respectively. Pheromone production began within several days after males were placed onto diet medium and continued for at least 20 weeks. Peak production was 〉3 µg total pheromone per male per day. Males in groups of 50–60 emitted less pheromone (the peak level was 0.09 µg per beetle per day), and the emissions from groups contained relatively little tetraene (proportions of the components listed above were 100:7:2:7, respectively). Three additional trienes and one additional tetraene were identified in minor amounts; the entire eight-component male-specific blend is qualitatively identical and quantitatively similar to that of the North American sibling species,C. freemani Dobson. A synthetic blend of the four major components on rubber septa, prepared to emit in the same proportions as from individual males, was highly attractive in the field when synergized with fermenting whole-wheat bread dough. Cross-attraction was observed in the field involving the pheromones ofC. davidsoni, C. hemipterus (L.), andC. mutilatus Erichson. Potential uses of the pheromones in pest management are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 14 (1987), S. 603-607 
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fractional dietary Ca absorption, ‘a’, is measured by determining the ratio of two stable isotopic tracers, one of them orally (44Ca @ 0.2-0.5 mg/kg) and the other intravenously (42Ca @ 0.02-0.1 mg/kg). Thermal ionization mass spectrometry (TIMS) is used to measure the perturbation of natural abundance isotope ratios (delta % excess). Typical sensitivity of the TIMS permits detection of a 2.5 delta % excess change from the natural Ca isotope ratio with relative standard deviations of about 0.5%. At sufficiently long times absorption becomes constant so that ‘a’ is determined by a product of constants and a measured ratio.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-1561
    Keywords: Carpophilus hemiplerus ; C. mutilatus ; C. davidsoni ; C. humeralis ; Coleoptera ; Nitidulidae ; aggregation pheromones ; stone fruit ; phenology ; dose
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Synthetic aggregation pheromones ofCarpophilus hemipterus (L.) andCarpophilus mutilatus Erichson were field tested during a 10-month period in southern New South Wales stone fruit orchards to determineCarpophilus spp. phenology and the effect of two pheromone doses on attraction. Aggregation pheromones synergize the attraction of host volatiles toCarpophilus spp. Four major species,C. hemipterus, C. mutilatus, C. davidsoni Dobson andC. (Urophorus) humeralis (F.), were trapped, with greater numbers of each species inC. hemipterus pheromone/fermenting whole-wheat breaddough-baited traps, than in dough-only-traps. InC. mutilatus pheromone/ fermenting-dough-baited traps, onlyC. mutilatus andC. davidsoni responded in greater numbers than to dough-only traps. Beetles first appeared in traps in late September (early spring) when daily maximum temperatures averaged 17.5
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-1561
    Keywords: Attractant ; alcohol ; aldehyde ; geranic acid ; monitoring ; aggregation pheromone ; Anthonomus eugenii ; pepper weevil ; Coleoptera ; Curculionidae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract This study describes the identification of an aggregation pheromone for the pepper weevil,Anthonomus eugenii and field trials of a synthetic pheromone blend. Volatile collections and gas chromatography revealed the presence of six male-specific compounds. These compounds were identified using chromatographic and spectral techniques as: (Z)-2-(3,3-dimethylcyclohexylidene)ethanol, (E)-2-(3,3-dimethylcyclohexylidene)ethanol, (Z)-(3,3-dimethylcyclohexylidene)acetaldehyde, (E)-(3,3-dimethylcyclohexylidene)acetaldehyde, (E)-3,7-dimethyl-2,6-octadienoic acid (geranic acid), and (E)-3,7-dimethyl-2,6-octadien-1-ol (geraniol). The emission rates of these compounds from feeding males were determined to be about: 7.2, 4.8, 0.45, 0.30, 2.0, and 0.30µg/male/day, respectively. Sticky traps baited with a synthetic blend of these compounds captured more pepper weevils (both sexes) than did unbaited control traps or pheromone-baited boll weevil traps. Commercial and laboratory formulations of the synthetic pheromone were both attractive. However, the commercial formulation did not release geranic acid properly, and geranic acid is necessary for full activity. The pheromones of the pepper weevil and the boll weevil are compared. Improvements for increasing trap efficiency and possible uses for the pepper weevil pheromone are discussed. A convenient method for purifying geranic acid is also described.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-1561
    Keywords: Carpophilus mutilatus ; Carpophilus davidsoni ; Carpophilus hemipterus ; Coleoptera ; Nitidulidae ; aggregation pheromones ; mass-trapping ; stone fruit ; population suppression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Experiments were conducted in southern New South Wales to evaluate the potential of mass-trapping using synthetic aggregation pheromones and a coattractant as a control option forCarpophilus spp. in stone fruit orchards. A cordon of 54 pipe and 54 funnel traps (one trap of each type per perimeter tree) baited with pheromones ofC. mutilatus andC. davidsoni and coattractant (fermenting bread dough) was maintained around an apricot orchard for three weeks prior to harvest. The incidence ofCarpophilus spp. in ripe fruit in the center of the orchard was significantly reduced compared to a nearby orchard or the perimeter trees containing traps. A cordon of 16 water-filled Magnet funnel traps baited with pheromones ofC. mutilatus andC. davidsoni and coattractant was placed around a 9 × 9 block of trees in a peach orchard (single traps on alternate perimeter trees). This trapping regime significantly reduced infestation of fruit baits byCarpophilus spp. in the center tree over a period of six weeks compared to fruit baits in trap trees and distant (100 m) control trees. However, cordons of eight pheromone traps within 1 m of single trees or a single trap adjacent to a tree increasedCarpophilus spp. infestation of fruit baits by up to 7.5 × compared to trees without pheromone traps. Mass-trapping based on perimeter positioning of pheromone traps (at a yet to be determined distance from protected trees) appears to show potential as a control strategy forCarpophilus spp. in stone fruit orchards during fruit ripening and harvest but traps too close to trees must be avoided. Development of a strategy for population suppression is discussed with respect to trap type, efficacy, positioning, and density; pheromone and coattractant delivery systems; and orchard sanitation.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 7 (1994), S. 705-711 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An infrared spectroscopic study of the 1 : 1 hydrogen-bond association of amidates with both methanol and 4-fluorophenol showed that the site of complexation is the oxygen of the amidate function. However the formamidate HCON2Me3 forms a second 1 : 1 complex on the nitrogen of the amidate. The formation constants of the hydrogen-bond complexes of the amidates with the reference hydrogen-bond donor 4-FC6H4OH indicate that the amidates are stronger hydrogen-bond bases than are amides and amide vinylogues. As such, the amidates constitute the strongest carbonyl bases hitherto investigated on the hydrogen-bond basicity scale.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An IR spectroscopic study of the hydrogen bonding of Bu3N+N-C≡N with 4-fluorophenol showed that the site of complexation is the nitrogen of the nitrile function. THe formation constant of the 1:1 complex in CCl4 indicates that this cyanamidate is a stronger hydrogen-bond base than is any nitrile, amine or pyridine. The Bu3N+-N- group increases the basicity of the nitrile group very efficiently because of the conjugation of two lone pairs on the anionic nitrogen with the π systems of the cyano group. This conjugation is also exemplified by the very low ν(C≡N) wavenumber (2104 cm-1).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 8 (1994), S. 876-880 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The electron ionization mass spectra of fourteen 4-substituted (4-X) camphors have been recorded and analyzed using metastable ion analysis and exact mass measurement. With respect to camphor, alkyl substituents changed the relative importance of different fragmentation pathways, though they did not induce new fragmentations. Substituents X connected to the camphor framework through an atom having a lone pair of electrons were generally lost as HX. Overall the fragmentation behaviour was essentially independent of the inductive substituent constant. Under chemical ionization conditions, only methane of the reagent gases produced extensive fragmentations of these compounds; isobutane, acetone and ammonia were ineffective. The nature of the fragmentations was independent of both the inductive substituent constant of the substituent X and the proton affinity and heat of formation of the corresponding neutral compound HX.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 22 (1993), S. 181-183 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In 10 mM sodium phosphate, pH 7.6, containing 0.1 mM ethylenediaminetetraacetic acid, ions corresponding to the non-covalent, four-stranded oligonucleotide, d(CGCG4GCG)4, were detected by negative ion electrospray ionization (ESI) mass spectrometry at a low nozzle-skimmer (ΔNS) bias (-150 V), but not at a higher ΔNS bias (〉 -250 V). In contrast, when the sample was desalted and analyzed by ESI mass spectrometry at a low ΔNS bias only ions for the single-stranded d(CGCG4GCG) species were observed. These data agree with spectroscopic evidence which showed that oligonucleotides with the sequence motif 5′d(CGCGnGCG)3′, where n = 2-5, formed stable four-stranded complexes in the presence of monatomic cations, like K+, Ca2+, Na+ and Li+, but not in their absence.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1040-7685
    Keywords: chiral ; separation ; micellar ; capillary ; electrophoresis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This article describes the synthesis of a novel chiral surfactant based on (R,R)-tartaric acid. (R,R)-Tartaric acid is acetylated while simultaneously forming a cyclic anhydride, which is then reacted with n-decylamine forming a chiral, long chain carboxylic acid. This carboxylic acid is then further reacted with the achiral amino acid taurine forming the required surfactant which has a sulfonic acid headgroup. Evidence for its surface activity and an estimate of its critical micelle concentration (cmc) have been obtained using surface tension measurements and conductivity. The surfactant has then been used as the additive in micellar electrokinetic capillary chromatography (MECC) to achieve chiral separations of compounds with multiple aromatic functionality. These separations are compared with those achieved with previously reported tartaric acid based surfactants which show a difference in selectivity. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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