ISSN:
0009-2940
Keywords:
Resolution, optical / Stationary phase, Chiral / Anylose carbamates / Celluslose carbamates / [3.2]Paracyclophanes, functionalized
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Optical resolution of 22 [2,2]paracyclophane derivatives was examined by high-performance liquid chromatography (HPLC) using tris(3,5-dimethylphenylcarbamates) of cellulose and amylose as chiral stationary phases. Most compounds were completely separated into enantiomers at least on one of the stationary phases. The preparation of hte new cyclophane derivatives 10, 11, 12, 14, 16, and 19 as wel as a new procedure for the synthesis of 4-fluoro-[2,2]paracyclophane (3) are described.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230432
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