ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Formation and N.M.R.-Spectroscopic Characterization of Alk-(ar-)oxy Derivatives of Trichlorophosphazene-N-phosphoryldichloride, Cl3P=N—P(O)Cl2, Imido- and N-Methylimidodiphosphoryltetrachloride, Cl2P(O)NHP(O)Cl2 and Cl2P(O)N(CH3)P(O)Cl2The ester chlorides and esters P2NOCl5-x(OR)x (x = 1-5), P2(NH)O2Cl4-x(OR)x (x = 1-4) and P2(NCH3)O2Cl4-x(OR)x (x = 1-4) derived from the title compounds by substitution of chlorine atoms by alk- or aroxy groups are characterized by their 31P-n.m.r. data. The possibilities for forming these compounds by alcoholysis, chloridolysis, dealkylation and P—N-bond formation are discussed.
Notes:
Die sich von den Titelverbindungen durch Substitution der Chloratome durch Alk- bzw. Aroxygruppen ableitenden Esterchloride und Ester P2NOCl5-x(OR)x (x = 1-5), P2(NH)O2Cl4-x(OR)x (x = 1-4) und P2(NCH3)O2Cl4-x(OR)x(x = 1-4) werden 31P-NMR-spektroskopisch charakterisiert. Die Möglichkeiten zur Bildung dieser Verbindungen durch Alkoholyse, Chloridolyse, Entalkylierungs- und P—N-Bindungsknüpfungsreaktionen werden vorgestellt.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19845110404
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