ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract CpMoFeCo(CO)7(μ3-S) reacts with Cp*M(CO)3Cl or CpM(CO)3Cl (M = W, Mo) to gave the mixed-metal clusters Cp*WCpMoFe(CO)7(μ3-S) (1), Cp*MoCpMoFe(CO)7(μ3-S) (2), CpWCp*MoFe(CO)7(μ3-S) (3), CpMoCp*MoFe(CO)7(μ3-S) (4) and Cp*WCp*MoFe(CO)7(μ3-S) (5). The title clusters have been characterized by i.r., 1H/13C-n.m.r. spectroscopy and their compositions have been confirmed by elemental analyses. The X-ray crystal structure analysis shows the two independent enantiomeric molecules of clusters (1) in one crystal structure unit.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1007072901162
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