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  • Electronic Resource  (53)
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  • Electronic Resource  (53)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 3276-3283 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of substrate preparation on the structure and orientation of MgO films grown on (001) GaAs using pulsed laser deposition has been investigated. Textured MgO films displaying a (111)MgO(parallel)(001)GaAs orientation relation with x-ray rocking curve full width at half maximum (FWHM) values as low as 1.8° were obtained in cases where the native GaAs surface oxide was only partially desorbed prior to growth. Reflection high-energy electron diffraction, transmission electron microscopy (TEM), and x-ray pole figure analysis of these films reveals a preferential orientation within the plane of the substrate: [11¯0]MgO(parallel)[11¯0]GaAs and [112¯]MgO(parallel)[110]GaAs. An interfacial layer (∼5 nm thick) was observed in high resolution TEM analysis, and was attributed to a remnant native GaAs oxide layer. Complete desorption of the native GaAs oxide at ∼600 °C in vacuum prior to MgO growth led to significant surface roughening due to Langmuir evaporation, and resulted in randomly oriented polycrystalline MgO films. Growth of MgO on Sb-passivated GaAs substrates, which provided smooth, reconstructed surfaces when heated to 350 °C in vacuum, resulted in cube-on-cube oriented films [i.e., (001)MgO(parallel)(001)GaAs,[100]MgO(parallel)[100]GaAs] with x-ray rocking curve FWHM values as low as 0.47°. TEM analysis of the cube-on-cube oriented films revealed evidence of localized strain fields at the MgO/GaAs interface, indicating the presence of misfit dislocations in the MgO layer.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 6012-6019 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Twin related domain formation is examined as a strain relaxation mechanism for a heteroepitaxial tetragonal film on a cubic substrate. Elastic relaxations are calculated for a single twin band in which the c axis of the tetragonal domains is either related by a 90° rotation about an axis in the plane of the film or by a 90° rotation about the surface normal. In all cases, the strain energy change is evaluated for both the film and the substrate. A domain pattern map is developed that predicts single domain and multiple domain fields depending on the relative misfit strains and domain wall energy. The concept of a critical thickness, hc, for domain formation is developed. For cases in which the c axis is rotated 90° about an axis in the plane of the film, the critical thickness depends only on the relative coherency strain between the substrate and film and the ratio of the domain wall energy to the stored elastic energy. For the case of a pattern consisting of energetically equivalent domains with the c axis in plane, the equilibrium distance of multiple domains is derived. For such multiple domains, a minimum wall separation distance exists that depends nonlinearly on the film thickness.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 7261-7267 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The crystallography and microstructure of an antiferroelectric ceramic of approximate composition Pb0.97La0.02(Zr0.65Sn0.25Ti0.10)O3 have been examined. Transmission electron microscopy (TEM), x-ray, and neutron powder studies were carried out. The cell is metrically tetragonal with a c/a ratio of 0.993 when indexed to the parent cubic perovskite cell. The structure exhibits both a commensurate supercell, believed to be associated with oxygen octahedra distortions, and an incommensurate modulation. The different crystallographic variants of the tetragonal antiferroelectric phase gave rise to a hierarchy of domain structures. Charging of TEM specimens having an incomplete conductive coating caused domain migration.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 1933-1943 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We propose and investigate a model for the development of cross-hatch surface morphology in growing mismatched layers. The model incorporates two important elements: (i) strain relaxation due to dislocation glide in the layer (film) interior that is also associated with misfit dislocation formation at the film/substrate interface and (ii) lateral surface transport that eliminates surface steps that originated from dislocation glide. A combination of dislocation-assisted strain relaxation and surface step flow leads to the appearance of surface height undulations during layer growth. A Monte Carlo simulation technique was applied to model dislocation nucleation events in the course of strain relaxation. The simulation was used to model the influence of dislocations on film surface height profiles. The surface height displacement was calculated from the analytic elasticity solutions for edge dislocations near a free surface. The results of the modeling predict that the average amplitude of the surface undulations and their apparent wavelength both increase with increasing film relaxation and film thickness. The developed cross-hatch pattern is characterized by an atomically smooth but mesoscopically (lateral dimensions ∼0.1–10 μm) rough surface morphology. The conclusions of the model are in agreement with atomic force microscopy observations of cross-hatch surface relief in In0.25Ga0.75As/GaAs samples grown well beyond the critical thickness for misfit dislocation formation. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Two schemes of nucleation and growth of gallium nitride on Si(111) substrates are investigated and the structural and electrical properties of the resulting films are reported. Gallium nitride films grown using a 10–500 nm-thick AlN buffer layer deposited at high temperature (∼1050 °C) are found to be under 260–530 MPa of tensile stress and exhibit cracking, the origin of which is discussed. The threading dislocation density in these films increases with increasing AlN thickness, covering a range of 1.1 to 〉5.8×109 cm−2. Films grown using a thick, AlN-to-GaN graded buffer layer are found to be under compressive stress and are completely crack free. Heterojunction field effect transistors fabricated on such films result in well-defined saturation and pinch-off behavior with a saturated current of ∼525 mA/mm and a transconductance of ∼100 mS/mm in dc operation. © 2001 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 6470-6476 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The surfaces of GaN films grown by metalorganic chemical vapor deposition (MOCVD) and molecular beam epitaxy (MBE) were studied using atomic force microscopy (AFM). Due to the high dislocation densities in the films (108 cm−2), the typical surface morphologies of layers grown by both techniques were dominated by three dislocation mediated surface structures—pinned steps, spiral hillocks, and surface depressions. The characteristics of these surface structures were found to depend on growth technique (MOCVD vs MBE) and the group-III to group-V ratio used in the growth of MBE GaN films. Pinned steps, created by the intersections of mixed character dislocations with the free surface, were found on all GaN films. The pinned steps were observed to be predominantly straight on the MOCVD GaN and curved into spiral hillock formations on the MBE GaN. Spiral growth hillocks form when pinned steps grow outward and around the dislocation under step-flow growth conditions. The tightness of the spiral hillocks on MBE GaN surfaces was found to increases with III/V ratio. Surface depressions, caused by the high strain-energy density near dislocations, were also observed on the surfaces of the GaN films. Two characteristic depression sizes were found on all MOCVD GaN films whereas depressions were observed only on MBE GaN films grown with low III/V ratios. These observations are explained using theories developed by Burton, Cabrera, and Frank [Philos. Trans. R. Soc. London, Ser. A 243, 299 (1951)] and Frank [Acta Crystallogr. 4, 497 (1951)]. © 1999 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 3808-3816 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In the heteroepitaxial growth of films with large misfit with the underlying substrate (linear mismatch strains in excess of 1%–2%) the generation of misfit dislocations and threading dislocations (TDs) is ubiquitous for thicknesses well in excess of the equilibrium critical thickness. Experimental data suggest that the TD density in relaxed homogeneous buffer layers can be divided into three regimes: (i) an entanglement region near the film/substrate interface corresponding to TD densities of ∼1010–1012 cm−2; (ii) a falloff in TD density that is inversely proportional to the film thickness h, applicable to densities in the range ∼107–109 cm−2; and (iii) saturation or weak decay of the TD density with further increase in film thickness. Typical saturation densities are on the order of ∼106–107 cm−2. In this article, we show that the TD reduction may be described in terms of effective lateral motion of TDs with increasing film thickness. An analytic model is developed that successfully predicts both the 1/h scaling behavior and the saturation of TD densities. Long-range fluctuations in the net Burgers vector content of the local TDs is a cause for saturation behavior. These models are supported by computer simulations. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 3228-3237 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Defect structures were investigated by transmission electron microscopy for GaN/Al2O3 (0001) epilayers grown by metal-organic chemical vapor deposition using a two-step process. The defect structures, including threading dislocations, partial dislocation bounding stacking faults, and inversion domains, were analyzed by diffraction contrast, high-resolution imaging, and convergent beam diffraction. GaN film growth was initiated at 600 °C with a nominal 20 nm nucleation layer. This was followed by high-temperature growth at 1080 °C. The near-interfacial region of the films consists of a mixture of cubic and hexagonal GaN, which is characterized by a high density of stacking faults bounded by Shockley and Frank partial dislocations. The near-interfacial region shows a high density of inversion domains. Above ∼0.5 μm thickness, the film consists of isolated threading dislocations of either pure edge, mixed, or pure screw character with a total density of ∼7×108 cm−2. The threading dislocation reduction in these films is associated with cubic to hexagonal transformation of the nucleation layer region during high temperature growth. © 1996 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 4037-4049 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The micromechanics of the lamellar ...a1/a2/a1/a2... domain pattern are developed for the case of epitaxial tetragonal ferroelectric or ferroelastic films grown on (001) substrates. This problem is treated in the framework of the theory of defects. Coherency defects are necessary to maintain epitaxy as a result of the symmetry-reducing phase transition in the film (ferroelectric or ferroelastic transition). The defects include continuous distributions of edge and screw dislocations. The screw dislocation distributions are equivalent to an alternating Somigliana dislocation chain. Using this approach, fully analytic solutions are derived for the stress and strain in the film and substrate. These calculations include all the effects of the free surface. An integral expression is derived for the elastic energy. Using dipole and quadrupole approximations, analytic expressions are derived for the rotations of the crystal axes for individual domains, the elastic energy, and thickness dependence of the domain periodicity. We find, in agreement with previous work, that there is no critical thickness to form the ...a1/a2/a1/a2... domain pattern. For thick films the domain periodicity scales with the square root of the film thickness. © 1996 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 1405-1415 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Experimental evidence is presented to verify the quantitative predictions of interfacial defect theory as applied to strain relief in epitaxial PbTiO3 thin films through the formation of 90° domains. Epitaxial PbTiO3 thin films grown by metal-organic chemical vapor deposition on MgO(001), SrTiO3(001), LaAlO3(001), and SrRuO3(001)/SrTiO3(001) substrates are examined using four-circle x-ray diffraction and transmission electron microscopy. The data represents a detailed examination of the ...c/a/c/a... 90° domain patterns that develop during the paraelectric to ferroelectric (PE→FE) phase transition as the film is cooled from the growth temperature. Three independent measurements of the relative coherency strain (er) are reported. The data quantitatively and self-consistently verify the crystallographic rotations predicted by the concept of the relative coherency strain and demonstrate the validity of domain stability maps in understanding the phase transformation history in epitaxial ferroelectric thin films. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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