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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 1517-1522 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Expitaxial ferroelectric BaTiO3 thin films have been grown on (001) MgO and MgO-buffered (001) GaAs substrates by pulsed laser deposition to explore the effect of substrate lattice parameter. X-ray-diffraction studies showed that the BaTiO3 films on both MgO single-crystal substrates and MgO-buffered (001) GaAs substrates have a cube-on-cube epitaxy; however, for the BaTiO3 films grown on MgO the spacing of the planes parallel to the substrate was close to the c-axis dimension of the unconstrained tetragonal phase, whereas the BaTiO3 films on MgO/GaAs exhibited a spacing closer to the a-axis dimension of the unconstrained tetragonal phase. The cube-on-cube epitaxy was maintained through the heterostructures even when thin epitaxial intermediate buffer layers of SrTiO3 and La0.5Sr0.5CoO3 were used. The intermediate layers had no effect on the position of the BaTiO3 peak in θ-2θ scans. Together, these observations indicate that, for the materials combinations studied, it is the thermal-expansion mismatch between the film and the underlying substrate that determines the crystallographic orientation of the BaTiO3 film. Preliminary measurements indicate that the BaTiO3 films are "weakly'' ferroelectric. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 3276-3283 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of substrate preparation on the structure and orientation of MgO films grown on (001) GaAs using pulsed laser deposition has been investigated. Textured MgO films displaying a (111)MgO(parallel)(001)GaAs orientation relation with x-ray rocking curve full width at half maximum (FWHM) values as low as 1.8° were obtained in cases where the native GaAs surface oxide was only partially desorbed prior to growth. Reflection high-energy electron diffraction, transmission electron microscopy (TEM), and x-ray pole figure analysis of these films reveals a preferential orientation within the plane of the substrate: [11¯0]MgO(parallel)[11¯0]GaAs and [112¯]MgO(parallel)[110]GaAs. An interfacial layer (∼5 nm thick) was observed in high resolution TEM analysis, and was attributed to a remnant native GaAs oxide layer. Complete desorption of the native GaAs oxide at ∼600 °C in vacuum prior to MgO growth led to significant surface roughening due to Langmuir evaporation, and resulted in randomly oriented polycrystalline MgO films. Growth of MgO on Sb-passivated GaAs substrates, which provided smooth, reconstructed surfaces when heated to 350 °C in vacuum, resulted in cube-on-cube oriented films [i.e., (001)MgO(parallel)(001)GaAs,[100]MgO(parallel)[100]GaAs] with x-ray rocking curve FWHM values as low as 0.47°. TEM analysis of the cube-on-cube oriented films revealed evidence of localized strain fields at the MgO/GaAs interface, indicating the presence of misfit dislocations in the MgO layer.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 6470-6476 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The surfaces of GaN films grown by metalorganic chemical vapor deposition (MOCVD) and molecular beam epitaxy (MBE) were studied using atomic force microscopy (AFM). Due to the high dislocation densities in the films (108 cm−2), the typical surface morphologies of layers grown by both techniques were dominated by three dislocation mediated surface structures—pinned steps, spiral hillocks, and surface depressions. The characteristics of these surface structures were found to depend on growth technique (MOCVD vs MBE) and the group-III to group-V ratio used in the growth of MBE GaN films. Pinned steps, created by the intersections of mixed character dislocations with the free surface, were found on all GaN films. The pinned steps were observed to be predominantly straight on the MOCVD GaN and curved into spiral hillock formations on the MBE GaN. Spiral growth hillocks form when pinned steps grow outward and around the dislocation under step-flow growth conditions. The tightness of the spiral hillocks on MBE GaN surfaces was found to increases with III/V ratio. Surface depressions, caused by the high strain-energy density near dislocations, were also observed on the surfaces of the GaN films. Two characteristic depression sizes were found on all MOCVD GaN films whereas depressions were observed only on MBE GaN films grown with low III/V ratios. These observations are explained using theories developed by Burton, Cabrera, and Frank [Philos. Trans. R. Soc. London, Ser. A 243, 299 (1951)] and Frank [Acta Crystallogr. 4, 497 (1951)]. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 316-318 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: True solar-blind operation with a sharp responsivity cutoff at ∼300 nm has been demonstrated in AlGaN-based photodiodes using an "inverted heterostructure photodiode" design. This structure utilizes an AlxGa1−xN(x〉0.3) intrinsic or lightly doped active layer surrounded by p- and/or n-type contact layers having a narrower band gap than the active layer. By utilizing narrow band gap (e.g., GaN) contact layers, the difficulties associated with achieving high doping efficiencies in wide band gap contact layers are circumvented. This basic structure is applicable to both front- and back-side illuminated detector geometries. Front-side illuminated solar-blind photodiodes were demonstrated with a peak responsivity of 0.08 A/W at 285 nm, while back-side illuminated detectors yielded a peak responsivity of 0.033 A/W at 275 nm (both are measured without antireflection coating). Both types of detectors offered sharp spectral responsivity cutoff of at least three orders of magnitude by 325 nm. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 490-492 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The lattice parameter and surface morphology of homoepitaxial SrTiO3 films were found to depend on the ambient oxygen pressure during growth. The homoepitaxial layers were grown by pulsed laser deposition with static ambient oxygen pressures of 100, 10, and 1 mTorr. The surface roughness of the films increased with increasing ambient growth pressure. In each case, the measured out-of-plane lattice parameter of the film was larger than that of the substrate. The mismatch between film and substrate increased with decreasing growth pressure. Compressive stresses of ∼0.28, 1.2, and 2.0 GPa were determined for homoepitaxial SrTiO3 layers deposited at 100, 10, and 1 mTorr, respectively. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 5472-5479 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structure, morphology, and optical properties of homoepitaxial GaN layers grown by molecular beam epitaxy on metalorganic chemical vapor deposition (MOCVD)-grown GaN "template" layers were investigated as a function of the group III/group V flux ratio during growth. GaN layers grown with a low III/V ratio (N-stable growth) displayed a faceted surface morphology and a tilted columnar structure with a high density of stacking faults. In contrast, films grown with a high III/V ratio (Ga-stable growth) displayed comparable structure to the underlying MOCVD-grown template. The transition from N-stable to Ga-stable growth modes was found to occur over a narrow range of Ga fluxes at a growth temperature of 650 °C. Evidence of Ga accumulation and step-flow growth was observed for films grown under Ga-stable conditions, leading to the formation of spiral growth features at the surface termination of mixed edge/screw dislocations. Photoluminescence measurements indicate that the deep-level (∼550 nm) emission is increased relative to the near-band edge emission for films grown under N-stable conditions. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 62 (1993), S. 2332-2334 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Oriented In2O3 films have been grown on (001) InAs, MgO, and YSZ substrates using pulsed laser deposition. The films in each case displayed a cube-on-cube orientation relation with respect to the substrate, as determined by in situ RHEED analysis and x-ray θ–2θ measurements. X-ray rocking curve full width at half-maximum values as low as 1.3°, 1.5°, and 0.29° have been obtained for In2O3 layers on InAs, MgO, and YSZ, respectively. An oriented native surface oxide layer was employed to provide an appropriate epitaxial template for aligned growth of In2O3 on InAs substrates, while growths were carried out directly on MgO and YSZ. The not intentionally doped films displayed resistivities on the order of 10−4 Ω cm, with Hall mobilities of 50 cm2/V s measured for In2O3 deposited on YSZ substrates.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 490-492 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Results of growth of InAs on a superconducting TlCaBaCuO (2-1-2-2) thin film are reported. The InAs was grown by molecular beam migration-enhanced epitaxy at a substrate temperature of 250 °C. The Tc(zero) of the Tl film before and after InAs deposition was 106 and 100 K, respectively. X-ray diffraction and reflection electron microscopy studies showed the InAs to be polycrystalline, having grains in the 300 A(ring) size range. This is the first report of deposition of a III-V semiconductor on superconductor, without significant degradation of Tc.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 3588-3590 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth of epitaxial MgO films on Sb-passivated (001)GaAs using pulsed laser deposition has been investigated. The temperature at which the Sb-passivation layer was desorbed was found to have a significant effect on the interfacial properties of MgO/GaAs heterostructures. Heating the substrates to 350–380 °C in vacuum resulted in a (1×3) GaAs surface reconstruction suitable for the growth of epitaxial MgO films. However, residual Sb was found to persist on the GaAs surface at temperatures as high as 500 °C. MgO growth after Sb desorption at 350–380 °C resulted in a nonuniform interfacial layer which varied in thickness from ∼0.1 to 1.5 nm, whereas substrates heated to 500 °C prior to MgO growth displayed abrupt interfaces. Capacitance–voltage measurements indicated a qualitative difference in the interfacial electronic properties for the two cases. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 405-407 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Highly oriented InAs films have been grown on natural diamond by MBE. InAs growths were carried out on diamond and on lattice-matched III–V substrates at 250, 300, and 470 °C. The highest quality films (smoothest surface and highest degree of crystallinity) were obtained at 300 °C. X-ray diffraction data indicate that the films have a strong [111] surface normal orientation. RHEED data indicate that the InAs forms a polyvariant thin film with alignment parallel to the interface of one of the 〈110〉InAs directions with one of the 〈110〉diamond directions.
    Type of Medium: Electronic Resource
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