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  • 1975-1979  (7)
  • 1976  (7)
  • Inorganic Chemistry  (5)
  • Polymer and Materials Science  (2)
  • Synthesis
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 109 (1976), S. 268-273 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Enehydrazines, 131) Some Products from Methyl 3-Hydroxy-1-methyl-5-pyrazolecarboxylate and 1-Benzyl-3-hydroxypyrazoleSome esters and ethers of the 3-pyrazolones 1a, 2c and6a are Prepared. They are derived from the tautomeric 3-hydroxypyrazole forms in which the free starting compounds mostly occur. Some substitutions in 4-position are likewise described.
    Notes: Es werden einige Ester und Äther der 3-Pyrazolone 1a, 2c und 6a dargestellt, die sich von der tautomeren 3-Hydroxypyrazol-Form herleiten, in der auch die freien Ausgangsverbindungen vorliegen. Einige Substitutionen in 4-Stellung der 3-Hydroxypyrazole werden ebenfalls beschrieben.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 48 (1976), S. 1223-1223 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 10 (1976), S. 929-938 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The addition of up to 10 g gentamicin sulfate antibiotic powder to 60 g units of Simplex-P acrylic bone cement caused gradual, proportional decreases in the bulk mechanical properties of compressive and diametral tensile stengths. Water leaching of the antibiotic from the cement did not significantly decrease these strengths.Scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) showed the antibiotic to reside in the acrylic matrix as discrete particles not usually associated with internal porosity. The surface-sensitive flexural strength of a proprietary bone cement was lowered immediately by small quantities of antibiotic powder, and continued to decrease as doses of up to 10 g/unit were admixed. Water leaching caused channeling as the antibiotic was removed from the surface, but it did not create further changes in flexural strength.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 424 (1976), S. 257-264 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermal Behaviour of Li3MnO4. II. α- and β-Li2MnO3By thermal decomposition of Li3MnO4 we obtained two new forms of Li2MnO3: α-Li2MnO3 crystallizes due to Guinier-Simon photographs cubic face-centered with a = 4.092 Å, β-Li2MnO3 hexagonal with a = 4,93, c = 14.24 Å, c/a = 2.89. α-Li2MnO3 is paramagnetic with μ = 3,82 B.M. Below the Neel temperature (≈ 50 K) β-Li2MnO3 is antiferromagnetic. Effective Coordination Numbers, ECoN, are calculated and discussed.
    Notes: Durch thermische Zersetzung von Li3MnO4 wurden zwei neue Formen von Li2MnO3 erhalten: Nach Guinier-Simon-Aufnahmen kristallisiert α-Li2MnO3 kubisch-flächenzentriert mit a = 4,092 Å, β-Li2MnO3 hexagonal mit a = 4,93, c = 14,24 Å, c/a = 2,89. α-Li2MnO3 ist paramagnetisch mit μ = 3,82 B.M., β-Li2MnO3 ist unterhalb der NEEL-Temperatur von ≈ 50 K antiferromagnetisch. Effektive Koordinationszahlen, ECoN, werden berechnet und diskutiert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 424 (1976), S. 249-256 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermal Behaviour of Li3MnO4. I. α- and β-Li3MnO4Li3MnO4 exists, due to Guinier-Simon photographs in two forms: α-Li3MnO4 (sky-blue) is isotypic with LT-Li3VO4, β-Li3MnO4 with HT-Li3PO4 (lattice constants and parameters see text). Both forms show paramagnetic behaviour with μ = 2.68 resp. 2.77 B.M. (θ≈ 0 K). The Madelung Part of Lattice Energy, MAPLE, and Effective Coordination Numbers, ECoN, are calculated and discussed.
    Notes: Li3MnO4 tritt nach Guinier-Simon-Aufnahmen in zwei Formen auf: α-Li3MnO4 (himmelblau) ist isotyp mit LT-Li3VO4, β-Li3MnO4 (flaschengrün) mit HT-Li3PO4 (Gitterkonstanten und Parameter siehe Text). Beide Formen sind paramagnetisch mit μ = 2,68 bzw. 2,77 B.M. (θ jeweils 0 K). Der Madelunganteil der Gitterenergie, MAPLE, und Effektive Koordinationszahlen, ECoN, werden berechnet und diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 420 (1976), S. 40-50 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of CsTcO4CsTcO4 crystallizes orthorhombic with a = 5.727, b = 5.921 and c = 14.34 Å. Z = 4, space group Pnma (Nr. 62, I.T.). The metal positions were refined by single crystal data, the oxygen positions first determined: the CsTcO4 structure is a slight distortion of the scheelite arrangement (parameters: see text). The MADELUNG Part of Lattice Energy, MAPLE, „Mean Effective Ionic Radii“, MEIR, and Effective Coordination Numbers, ECoN, are calculated and discussed.
    Notes: CsTcO4 kristallisiert orthorhombisch mit a = 5,727, b = 5,921 und c = 14,34 Å, Z = 4, in der Raumgruppe Pnma (Nr. 62, I.T.). Die Lageparameter von Cs und Tc wurden aus Einkristalldaten verfeinert, die O-Positionen erstmals bestimmt (Parameter: vgl. Text). Es liegt eine Verzerrungsvariante des Scheelittyps vor. Der MADELUNG-Anteil der Gitterenergie, MAPLE, sowie „Mittlere Effektive Ionenradien“, MEIR, und Effektive Koordinationszahlen, ECoN, werden berechnet und diskutiert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 424 (1976), S. 128-132 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Oxoniobates (III). II. On the Knowledge of NaNbO2New prepared NaNbO2 crystallizes hexagonal, a = 2.958, c = 11.58, c/a = 3.91, Z = 2, LiNbO2 type of structure. The oxygen parameter z0 is determined by systematic calculations of the Madelung Part of Lattice Energy, MAPLE, and Effective Coordination Numbers, ECoN: z = 0.1345.
    Notes: Neu dargestelltes NaNbO2 kristallisiert hexagonal, a = 2,958, c = 11,58 Å c/a = 3, 91, Z = 2, im LiNbO2-Typ. Der Sauerstoff-Parameter z0 wird durch systematische Berechnungen des Madelunganteiles der Gitterenergie, MAPLE, und von Effektiven Koordinationszahlen, ECoN, zu z0 = 0, 1345 bestimmt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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