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  • 2000-2004
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  • 1975-1979  (3)
  • 1960-1964
  • 1979  (3)
Material
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  • 2000-2004
  • 1995-1999
  • 1985-1989
  • 1975-1979  (3)
  • 1960-1964
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 1 (1979), S. 325-328 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The cyclic sulfonium zwitterions (I) are very effective catalysts for the cyclotrimerization of isocyanates. Under certain conditions (high concentration of isocyanate in the reaction system or high reaction temperature) cyclic sulfonium zwitterions act as anionic initiators. This behavior is due to the reaction of the isocyanate with stabilizing molecules of water of cyclic sulfonium zwitterions followed by rapid polymerization of the initiator. This phenomenon can be easily utilized in the one-step preparation of stable NCO-terminated oligomers of difunctional isocyanates.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of elasticity 9 (1979), S. 397-424 
    ISSN: 1573-2681
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A model is constructed to analyze adhesive bond failure at the tip of an interface crack. The model is based on the assumption that there are zones of bounded cohesive tensile and shear stresses near a crack tip. Within the context of certain broad a-priori assumptions on the distributions of certain stress and displacement components in the cohesive zones, the requirement thatall stresses in the two materials remain bounded provides a method to compute the specific details for these zones. It is assumed that bond failure occurs when the extension of the bond fiber at the crack tip exceeds a critical value. For an interface crack in a uniform tension field computations for two alternate formulations suggest that this failure criterion is independent of the precise distribution of the cohesive stresses, but rather depends only upon their averaged values. Combined loading with a dominant tensile component has also been analyzed. If the critical extension of bond fibers and the maximum value of the cohesive tensile stress are known, the model provides the maximum allowable interface stresses for given crack dimension and material parameters.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 100 (1979), S. 147-157 
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Incorporation of (14C)choline and (3H)myo-inositol into the total lipid fraction, incorporation of (14C)acetate into the sterol fraction and incorporation of (3H)thymidine into DNA were studied in human lymphocyte cultures. Concanavalin A induced an increase in the incorporation of these labels with the following features: (a) Phospholipid synthesis was increased promptly. The lag time for the increase in sterol synthesis and DNA synthesis were 5 hours and 27 hours respectively; (b) The increase in phospholipid synthesis and sterol synthesis was proportional to ConA concentration initially. Cells treated with a high concentration of ConA showed very low levels of DNA synthesis; (c) The increase in phospholipid synthesis could be abolished immediately by α-Methyl-Mannoside. α-Methyl-Mannoside blunted but did not abolish the increase in sterol synthesis. α-Methyl-Mannoside enhanced DNA synthesis of those cells which had been treated by a high concentration of ConA; and (d) Selective inhibition of sterol synthesis with 25-hydroxycholesterol did not prevent the increase in phospholipid synthesis, but it blocked the increase in DNA synthesis. Supplement of LDL, HDL or total lipoproteins to lymphocyte cultures was effective in preventing the inhibition of DNA synthesis by 25-hydroxycholesterol. These results suggest that in lymphocyte activation by ConA phospholipid synthesis, sterol synthesis and DNA synthesis were sequentially increased. The rate of cellular commitment to mitogenesis was proportional to ConA concentrations. High concentrations of ConA arrested the cell growth at a postcommitment point in the G1 phase. Enhanced phospholipid synthesis was a precommitment event. Enhanced sterol synthesis was a postcommitment event and reflected the requirement of an increased cholesterol supply for the passage of cell growth through G1.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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