ISSN:
1434-4475
Keywords:
Azo0initiators
;
Decomposition rates
;
Differential scanning calorimetry (DSC)
;
Volumetry
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The decomposition of various symmetric and unsymmetric azo-initiators (1,1′-dichloro-1,1′-diphenyl-1,1′-azoethane, 2,2′-dichloro-2,2′-azopropane, 1,1′-dichloro-1,1′-azocyclohexane, 2,2′-diacetoxy-2,2′-azopropane, 1,1′-diacetoxy-1,1′-diphenyl-1,1′-azoethane, 1,1′-diacetoxy-1,1′-azocyclohexane, 2,2′-dipropionoxy-2,2′-azopropane, 2,2′-dicapronoxy-2,2′-azopropane, 4,4′-dimethyl-1,4′-azobutyrolactone, azoisobutyronitrile, 2-t-butylazo-2′-cyanobutan, 2-t-bytylazo-1′-cyanocyclohexan) in solution was studied in dependence of temperature. Volumetry and differential-scanning-calorimetry (DSC) were used to determine decomposition rates; first order kinetics was found in all cases.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00938374
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