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  • 1
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 47 (1991), S. 1114-1115 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 47 (1991), S. 2107-2109 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 24 (1994), S. 75-78 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A reinvestigation of the X-ray crystal structure of malonic acid (C3H4O4) has been made in the light of some observations arising from solid-state13C NMR studies on this compound. The unit cell parameters are:a=5.156(1),b=5.341(1),c=8.407(1) Å, α=71.48o (2), β=76.12o (2), γ=85.09o (2), space group $$P\bar 1$$ ,Z=2. The structure was solved by direct methods and refined by full-matrix least-squares refinement to a finalR value of 0.038 for 711 unique reflections withl〉3σ. The packing of the molecules involves dimeric hydrogen bonded association of each carboxyl group with a centrosymmetrically related neighbor. The angles O−C−O (123.3o and 124.8o, respectively) for the two carboxyl groups agree qualitatively with the values predicted from a linear relationship relating the observed σ22 component of the Carbon-13 NMR chemical shielding tensor for the carboxyl carbon atom to the bond angle O−C−O at the carbon atom.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 28 (1991), S. 95-101 
    ISSN: 1573-0867
    Keywords: Phosphate rock dissolution ; soil pH ; solution phosphorus ; phosphorus fractionation ; monocalcium phosphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Soil Samples were collected from a field experiment conducted to evaluate the agronomic effectiveness of a reactive phosphate rock (PR), Sechura sand, relative to that of monocalcium phosphate (MCP) at different soil pHs and rates of application. The samples were analysed for P soluble in the soil solution and bicarbonate extractable P. The rate of dissolution of PR was calculated from the data on the fractionation of inorganic P. In MCP plots P in the soil solution decreased sharply with time especially at low pHs and high rates of fertiliser application. In PR plots the concentration remained with time at the same as or a slightly higher level than that was found one month after application. Solution concentration of P was lower at very high rates of PR application than at intermediate rates. In both MCP and PR plots bicarbonate extractable P decreased with increasing pH. Bicarbonate extractable P was linearly related to MCP but not to PR applied. The rate of dissolution and the proportion of PR dissolved decreased with increasing rates of PR application but the amount dissolved increased. Phosphate dissolved at high level of PR application did not seem to enhance proportionately either the concentration of P in soil solution or bicarbonate extractable P.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 37 (1994), S. 69-78 
    ISSN: 1573-0867
    Keywords: fertilizer efficiency ; partially acidulated phosphate rocks ; permanent pastures ; phosphate rock
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Phosphate rocks partially acidulated either with H3PO4 or H2SO4 were compared against SSP or TSP as phosphate fertilizers for permanent pasture. Eleven field trials were conducted over periods of up to 6 yrs. Fertilizers were surface applied annually. Initial soil pHw values ranged from 5.5–6.3 and Soil P retention from 25% to 97%. The PRs used for partial acidulation were unground or ground North Carolina PR, ground Khouribga PR, and a blend of ground PRs of North Carolina, Arad and Khouribga PRs. From the DM yields, fertilizer substitution values were calculated: fertilizer substitution value was the ratio of total P applied as superphosphate to total P as PAPR required to produce the same DM yield. Rates of dissolution of the PR component of PAPRs were also determined in soils collected from two trials. Agronomic results demonstrated that 30% acidulated phosphoric PAPRs (about 50% of total P as water-soluble P) were as effective as TSP, when the PR acidulated was from unground North Carolina PR. Results from one field trial indicated that when PAPR was from ground North Carolina PR, 20% acidulated product (water-soluble P 30–40% of total P) was equally effective as TSP. Replacement of ground North Carolina PR by a less reactive Khouribga PR did not appear to decrease the yield. Results indicated that per unit P released into soil solution, PAPRs were more efficient fertilizers than TSP. With annual applications, fertilizer substitution value of PAPR 30% tended to increase with time. Sulphuric PAPRs prepared from North Carolina PR were generally inferior to phosphoric PAPRs containing similar amounts of water-soluble P. This was attributed to the presence of CaSO4 coatings.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 50 (1994), S. 827-829 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-0867
    Keywords: Phosphate rock ; soil pH ; andepts ; white clover ; ryegrass ; soil phosphorus ; monocalcium phosphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The agronomic effectiveness of an unground reactive phosphate rock from Sechura, Peru, was compared with that of monocalcium phosphate in a severely P deficient and highly P retentive soil (vitrandept) over a period of three years. Soil pHs were adjusted to pH 5.1, 5.3, 5.6 and 6.4. The sward consisted mostly of ryegrass (Lolium perenne) and white clover (Trifolium repens). Fertilisers were applied at six rates at pH 5.3 and three rates at other pHs in the first year. For two of the rates fertilisers were reapplied in the second year. Dry matter yields, P uptake and ground cover of clover were determined during the experimental period. In phosphate rock treated plots a negative linear relationship was obtained between soil pH and the logarithm of yield. The agronomic effectiveness of phosphate rock relative to monocalcium phosphate increased with time at all pHs. Calculated at fertiliser rates which produced near maximum yields, relative agronomic effectiveness at soil pHs 5.1, 5.3, 5.6 and 6.4 were respectively 58, 60, 18, and 5 in year one; 118, 125, 77 and 38 in year three. At pH 5.3, as the rate of application increased the relative agronomic effectiveness of the phosphate rock generally decreased in year one but was enhanced in the intermediate rates in years two and three. The data for ground cover of clover gave a similar trend to that for herbage yield and P uptake.
    Type of Medium: Electronic Resource
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