ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Mulliken's model for the intensity of charge-transfer absorption bands in donor/acceptor complexes is extended to transition-metal compounds. Attention is focused on the analysis of systems containing a central metal ion and symmetrically equivalent π-acceptor ligands. The theory is illustrated for a one-donor/two-acceptor complex in D2d point symmetry. Results are stated for symmetries of commonly occurring transition-metal compounds that display well-documented metal-to-ligand charge-transfer transitions.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560390308
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