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Digitale Medien

Charge-transfer intensity in complexes with symmetrically equivalent acceptors (1991)

Parker, W. L. ; Crosby, G. A.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 39 (1991), S. 299-308

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Details

ISSN: 0020-7608

Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Mulliken's model for the intensity of charge-transfer absorption bands in donor/acceptor complexes is extended to transition-metal compounds. Attention is focused on the analysis of systems containing a central metal ion and symmetrically equivalent π-acceptor ligands. The theory is illustrated for a one-donor/two-acceptor complex in D2d point symmetry. Results are stated for symmetries of commonly occurring transition-metal compounds that display well-documented metal-to-ligand charge-transfer transitions.

Zusätzliches Material: 1 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/qua.560390308

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