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Digitale Medien

An information theory-based evaluation of stationary phases developed for optical resolution of amino acids (1993)

Iwaki, K. ; Yamazaki, M. ; Nimura, N. ; [weitere]

Springer

Chromatographia 37 (1993), S. 156-158

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Details

ISSN: 1612-1112

Schlagwort(e): Chromatography, general ; Information theory ; Stationary phases ; Optical resolution of amino acids

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary Naphthylethylurea multiple-bonded chiral stationary phases prepared for the optimal resolution of p-bromophenylcarbamyl derivatives of enantiomeric amino acids are examined from the viewpoint of information theory. The criterion used is the function of mutual information (FUMI) which describes the precision of analysis as a function of peak shape (area and width), overlap and noise level. The length of the polyethyleneamine spacer in the chiral stationary phases is evaluated by the precision (FUMI) calculated from the peak shape and overlap. The best column is defined as the one which gives the highest precision. The temperature effect on the precision is also examined.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02275853

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