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  • 2005-2009
  • 1995-1999  (4)
  • 1880-1889
  • 1997  (4)
Material
Years
  • 2005-2009
  • 1995-1999  (4)
  • 1880-1889
Year
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 5333-5358 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The vibrational level structure and unimolecular dissociation dynamics of highly vibrationally excited X˜ 2A DCO were investigated using the method of stimulated emission pumping spectroscopy (SEP). Single vibration-rotation states were probed with excitation energies up to E(X˜)=18 200 cm−1, (approximate)12 700 cm−1 above the asymptotic D-CO dissociation limit. The vibrational level structure of the molecule was found to be determined by distinctive polyads arising from a 1:1:2 resonance between the CD stretching, CO stretching, and DCO bending vibrations. Anharmonic coupling mechanisms give rise to considerable level mixings, especially regarding the CD and CO stretching motion. Thus, only a minority of vibrational states can be unambiguously assigned. The spectral line shape profiles of (approximate)100 highly excited "resonance states" in the continuum above the D-CO dissociation limit were measured at high resolution. The profiles are homogeneously broadened. The unimolecular decay rates, obtained from the observed line widths, were observed to fluctuate by more than two orders of magnitude in a strikingly state specific manner. The decay rates on average increase with increasing vibrational excitation energy. The state resolved experimental data are compared to predictions of the microcanonical specific unimolecular rate coefficients calculated from different statistical models. Serious problems were encountered considering the calculation of the density of states of the molecules in the continuum region of the potential energy surface regarding the contribution of the disappearing oscillator. Despite tentative corrections, the calculated rate coefficients were to too high by one to two orders of magnitude. Overall, the unimolecular dynamics of DCO appears to conform to an intermediate case between the strictly vibrationally "mode specific" and the "statistical" limits. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 385 (1997), S. 236-239 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Recently there has been increasing evidence that polaronic charge carriers are present in the normal state of the layered copper oxides4'5. However, it is not clear whether these normal-state polaronic carriers condense into Cooper pairs. To show that this occurs, it is necessary to demonstrate ...
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-0794
    Keywords: C/1995 O1 Hale-Bopp ; comets ; infrared spectroscopy ; ISO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H2O, CO2 and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H2O:CO2:CO at 3 AU pre-perihelion. H2O is observed at high spectral resolution in the ν3 group of bands around 2.7 μm and the ν2 group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν3 band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H2O, CO2 and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 1028,3.5 × 1028 and ≈1.5 × 1029 s-1, respectively. This corresponds to H2O:CO2:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO2 rather than by H2O.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We review some of the assumptions made in the use of muon spin rotation in superconductors: i.e. that the muons are implanted at random positions in the flux lattice, remain static after implantation and do not appreciably affect the properties of the surrounding superconductor; also that the flux lines are straight and static, and that the observed muon rotation frequency spectrum reflects the microscopic distribution of field values. We shall show how evidence for and against the truth of these assumptions in particular cases may be obtained from the μSR results themselves or by comparison with other measurements, and how this in turn may lead to deeper understanding of flux line structure and motion in superconductors.
    Type of Medium: Electronic Resource
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