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Distance Dependence of Photoinduced Electron Transfer: Syntheses and Properties of Anthracene-Spacered Porphyrin-Quinone Cyclophanes (1998)

Staab, Heinz A. ; Hauck, Ralph ; Popp, Brigitta

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 631-642

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ISSN: 1434-193X

Keywords: Electron transfer, distance dependence of ; Anthracene-spacered porphyrin-quinone cyclophanes ; Syntheses ; Characterizations ; Structures ; Physical properties ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In our previous work on benzene- and naphthalene-spacered porphyrin-quinone cyclophanes[1][2], the dependence of electron-transfer rates on reduction potentials of the acceptors and oxidation potentials of the porphyrins was studied. The present paper, dealing with the distance dependence of electron transfer, reports on the synthesis of anthracene-spacered analogues and on the electron-transfer rates, which are found to be drastically reduced.

Type of Medium: Electronic Resource

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