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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 57 (1999), S. 831-838 
    ISSN: 1572-8943
    Keywords: ceria ; effective index ; electrical conductivity ; ion transport number of oxygen ; yttria
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Y2O3 has a crystal structure of c-type rare-earth oxide. Y2O3 does not show an oxide ionic conductivity. On the other hand, CeO2 based oxide is one of the most interesting of the fluorite oxides since the ionic conductivity of it is higher than that of yttria-stabilized zirconia. However, CeO2 based oxides are partially reduced and develop electronic conductivity under reduced atmosphere. In this study, the effective index for the improvement of ionic conductivity in Y2O3 and CeO2 systems was defined using ionic radii from the viewpoint of crystallography. The utility of this effective index on some electrical properties was investigated.
    Type of Medium: Electronic Resource
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