Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
115 (2001), S. 3647-3656
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The hyperfine spectra of the Na2 1 3Δg state have been recorded with sub-Doppler continuous wave (CW) perturbation facilitated optical–optical double resonance (PFOODR) spectroscopy via A 1∑u+∼b 3∏u mixed intermediate levels. The rotational lines into the N=14–51 levels of the 1 3Δg state observed previously [J. Mol. Spectrosc. 134, 50 (1989)] have four components for transitions between symmetric rotational levels or five components for transitions between antisymmetric rotational levels and the hyperfine coupling belongs to Hund's case bβS. For the low-N levels observed later, however, the hyperfine spectra are much more complicated. We have worked out the matrix elements of the molecular Hamiltonian in the case bβS basis. After taking into consideration spin–orbit, spin–spin, and spin–rotation interactions, we obtained a set of molecular constants for the Na2 1 3Δg state, with which we can reproduce the hyperfine spectra of both high- and low-N rotational levels. © 2001 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1388548
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