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  • 2015-2019
  • 1995-1999  (20)
  • 1960-1964  (5)
  • 1925-1929
  • 1830-1839
  • Polymer and Materials Science  (25)
  • 1
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dissolution of α-chymotrypsin in nonpolar organic solvents can be achieved using hydrophobic ion pairing, whereby the polar counterions are replaced by a stoichiometric number of detergent molecules. Using Aerosol OT[AOT, sodium bis(2-octyl)sulfosuccinate], it is possible to partition significant amounts of the enzyme into alkanes and chlorocarbons. Apparent solubility in isooctane is greater than 1 mg/mL (80 μM). Necessary conditions for achieving effective partitioning of α-chymotrypsin into these solvents are described. Using CD spectroscopy, it can be shown that the AOT-α-chymotrypsin (CMT) complex retains its native secondary and tertiary structure when dissolved in alkanes, and that the globular structure is stable to more than 100°C. In contrast, α-chymotrypsin unfolds at 54°C in aqueous solution. The relative solubility of the AOT-CMT complex in a variety of alkanes and chlorocarbons is also reported. The native structure of α-chymotrypsin is maintained in carbon tetrachloride, but not in methylene chloride or chloroform. © 1995 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2141-2149 
    ISSN: 0887-624X
    Keywords: polyimides ; 4-phenylethynylphthalic anhydride ; thermooxidative stability ; high-temprature MAS NMR ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of high glass transition temperature (Tg 〉 300°C), amorphous, soluble, poly-imide oligomers of controlled molecular weight endcapped with 4-phenylethynylphthalic anhydride endcapping agent is described. The 4-phenylethynylphthalic anhydride was employed to afford a higher curing temperature (380-420°C) which widens the processing window compared to unsubstituted acetylene-endcapped polyimides. The polyimides were synthesized via solution imidization techniques, using the ester-acid of various dianhydrides and aromatic diamines. A “ one-pot” procedure utilizing NMP as the solvent and o-dichlo-robenzene as the azeotroping agent reproducibly produced fully imidized, but yet soluble wholly aromatic polyimides. Thermally cured samples were prepared with gel contents of up to 98% that displayed good solvent resistance. Glass transition temperatures comparable to high molecular weight linear analogs were produced. These polyimides also show excellent thermal stability as judged by thermogravimetric analysis (TGA). Model phenylethynyl imide compounds were synthesized and used to follow and elucidate the nature of the products formed from the phenylethynyl curing by using high temperature magic-angle 13C nuclear magnetic resonance (MAS NMR). Preliminary results indicate that the cure reaction can be followed by MAS NMR. However, the nature of the products being formed during the curing process is difficult to determine by the solid-state MAS NMR alone. Differential scanning calorimetry (DSC) data clearly show that the model system does indeed melt and displays a wide window before the strong cure exotherm is observed. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 9 (1997), S. 909-913 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 8 (1996), S. 863-864 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 11 (1960), S. 601-616 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Flame spraying of aluminaCeramic coatings produced by the flame spraying process are intended to protect the basic material against corrosion, erosion and oxidation as well as to act as a thermal barrier. For this purpose, alumina was found to be particularly well suited because of its high melting point, hardness, chemical resistance and other favourable properties. With this material as a model substance, the basic processes encountered with the spraying of ceramic powders have been investigated. The investigations comprised the melting process in the flame jet, the composition, lattice structure and physical properties of the spray coating, and the adhesion of the latter on pure metals and alloys with different surface roughness conditions.Although the porosity of these coatings is small, it prevents them from offering complete protection against corrosion and oxidation. But the protection effect can be enhanced by using resistant intermediate metal or enamel layers, and by stabilizing the sprayed coating. Owing to their high abrasion resistance and thermal barrier effect, these coatings have already found a wide field of application.
    Notes: Nach dem Flammspritzverfahren hergestellte keramische Überzüge haben die Aufgabe, das Grundmaterial gegen Korrosion, Erosion and Oxydation zu schützen sowie als Wärmeschranke zu wirken. Besonders geeignet erweist sich hierfür Aluminiumoxyd wegen seines hohen Schmelzpunktes, seiner Härte, seiner chemischen Resistenz und anderer günstiger Eigenschaften. Mit diesem Material als Modellsubstanz wurden die grundlegenden Vorgänge beim Spritzen von Keramik-Pulvern verfolgt. Die Untersuchungen erstreckten sich auf den Schmelzvorgang im Flammstrahl, auf den Aufbau, die Gitterstruktur und die physikalischen Eigenschaften der Spritzschicht sowie auf deren Haftung auf Reinmetallen und Legierungen mit verschiedener Oberflächenaufrauhung.Die Überzüge bieten wegen ihrer, wenn auch geringen Porosität keinen vollständigen Schutz gegen Korrosion und Oxydation. Durch Verwendung von resistenten Zwischenschichten aus Metall oder Email und durch Stabilisierung der Spritzschicht kann die Schutzwirkung jedoch erhöht werden. Auf Grund ihrer Abriebfestigkeit und ihrer wärmedämmenden Wirkung haben die Überzüge bereits ein weites Anwendungsgebiet gefunden.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 51-58 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of large-diameter pipes made of hard polyethyleneWith the aid of numerous illustrations, the applications of polyethylene pipes of relatively large diameters are surveyed. A special account is given of the advantages which such pipes may offer under different installation conditions. Especially in the Scandinavian countries  -  Norway, Finland and Sweden  -  where pipes are laid in the open even during the winter months, the toughness of hard polyethylene, even at low temperatures, is found to be a particular advantage. A special problem is posed by the need for a reliable jointing of large-diameter pipes. It is shown that, if the necessary conditions are adhered to, and if suitable aids are used, it is possible to obtain reliable butt welds, both between one pipe and another, and between pipe and welding collar. Such welding collars can be made in different ways. For instance, a mould is filled with the aid of an extruder and a rough cast prepared which, after cooling, is machined on a lathe. Pipes made of hard polyethylene are used not only for drinking water pipes but also for special purposes, e. g. cable protection pipes. For this purpose, a special technique, known as jetting method, is sometimes used for laying pipes across water.
    Notes: Anhand einer großen Anzahl van Bildern wird über den Einsatz van Rohren relativ großen Durchmessers aus Hart-Polyäthylen berichtet. Dabei wird auch auf die Vorteile, die solche Rohre unter den verschiedensten Verlegebedingungen bieten, näher eingegangen. Gerade in skandinavischen Ländern wie Norwegen, Finnland und Schweden, wo auch während der Wintermonate Rohrverlegungen im Freien stattfinden, erweist sich die gute Zähigkeit von Hart-Polyäthylen auch in der Kälte von besonderem Vorteil. Ein besonderes Problem stellt die zuverlässige Verbindung von Rohren großen Durchmessers der. Es wird gezeigt, daß bei Einhaltung der erforderlichen Bedingungen und bei Verwendung geeigneter Hilfsgeräte einwandfreie Stumpfschweißungen sowohl der Rohre untereinander als auch von Rohr und Vorschweißbund erzielt werden können. Die Herstellung solcher Vorschweißbunde kann auf verschiedene Arten vorgenommen werden; z. B. wird mit Hilfe eines Extruders eine Form gefüllt und durch Pressen ein Rohling hergestellt, der nach dem Erkalten auf einer Drehbank bearbeitet wird. Neben der Verwendung van Rohren aus Hart-Polyäthylen für Trinkwasserleitungen werden sie auch für Spezialzwecke, wie z. B. Kabelschutzrohre, eingesetzt. Dabei wird in manchen Fällen eine besondere Verlegetechnik beim Durchqueren van Gewässern, das sog. Einspülverfahren, angewandt.
    Additional Material: 36 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 653-660 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The products of the atmospheric corrosion of some common metalsThe layers of corrosion products formed by atmospheric corrosion upon copper, zinc, and iron are essentially composed of crystallized products most of which have been known as ore minerals; further possible relations of this type are pointed out in Table 2. Upon aluminium, however, amorphous layers are formed which have been little explored so far. The author distinguishes between two different layers: (1) the primary oxide layers (passivation layers), the thickness of which is about 10-7 cm and which are directly and in general with a defined crystallographic orientation (epitaxy) intergrown with the crystallites of the metallic substrate; (2) the secondary layers which are much thicker and the chemical gross composition and phase composition are largely determined by impurities in the atmosphere.
    Notes: Die atmosphärisch gebildeten Korrosionsschichten auf Kupfer, Zink und Eisen sind überwiegend aus kristallisierten Verbindungen aufgebaut, die meist als Erzmineralien bekannt sind; Hinweise auf weitere mögliche Zusammenhänge dieser Art gibt Tafel 2. Auf Aluminium entstehen dagegen amorphe und dementsprechend noch recht wenig aufgeklärte Schichten. Es werden unterschieden: Die nur ˜ 10-7 cm starken, oxidischen Primäurschichten (= Passivierungsschichten), die mit den Kristalliten der Metallunterlage direkt und im allgemeinen kristallographisch orientiert (epitaktisch) verwachsen sind, und darüber die sehr viel dickeren Sekundärschichten, deren bruttochemische und Phasenzusammensetzung weitgehend durch Verunreinigungen der Luft (z. B. SO2) bestimmt wird.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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