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  • 2005-2009
  • 1995-1999  (3)
  • 27.70.+q  (1)
  • C/1995 O1 Hale-Bopp  (1)
  • Dicopper(I)-octa-μ3-halogeno-hexahalogeno-octahedro-hexamolybdate(II)  (1)
  • 1
    ISSN: 1434-601X
    Keywords: 27.70.+q ; 23.20.Ck
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Using an 11.4MeV/u136Xe beam of the UNILAC accelerator of GSI and anatW target, A=184 isobars were produced and separated by using an on-line mass separator. A new isomeric state was found in184Hf. This state decays with a half-life of 48(10) s and emits three γ-rays of 73, 482, and 555 keV as well as lower-lying cascade transitions. The hindrance of the 73 keV-E1 transition with ΔK=8 is compared with those of other even-even hafnium isotopes. The half-life of184Lu was estimated to be between 15 and 25s.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0794
    Keywords: C/1995 O1 Hale-Bopp ; comets ; infrared spectroscopy ; ISO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H2O, CO2 and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H2O:CO2:CO at 3 AU pre-perihelion. H2O is observed at high spectral resolution in the ν3 group of bands around 2.7 μm and the ν2 group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν3 band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H2O, CO2 and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 1028,3.5 × 1028 and ≈1.5 × 1029 s-1, respectively. This corresponds to H2O:CO2:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO2 rather than by H2O.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 663-669 
    ISSN: 0044-2313
    Keywords: Dicopper(I)-octa-μ3-halogeno-hexahalogeno-octahedro-hexamolybdate(II) ; crystal structure ; Mo6X14-group ; trigonal planar CuX3-group ; ionic conduction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Trigonal Planar CuX3-Groups in Cu2Mo6X14, X = Cl, Br, ICu2Mo6Cl14 (I), Cu2Mo6Br14 (II) and Cu2Mo6I14 (III) were synthesized by thermal treatment of corresponding mixtures of copper(I) and molybdenum(II) halides. The crystal structures were determined by single crystal X-ray analyses. I and II show isotypism, cubic, Pn3 (no. 201, sec. setting), Z = 4, I: a = 12.772(3) Å, II: a = 13.350(2) Å. III shows a new structural type, orthorhombic, Pbca (No. 61), Z = 4, a = 16.058(3) Å, b = 10.643(2) Å, c = 16.963(3) Å. Trigonal planar CuX3 units were found in I—III. Structural behaviour relations are discussed, especially with regard to ionic conductivity.
    Notes: Cu2Mo6Cl14 (I), Cu2Mo6Br14 (II) und Cu2Mo6I14 (III) wurden durch thermische Behandlung der Gemenge der binären Halogenide CuX und Mo6X12 im molaren Verhältnis 2:1 in einkristalliner Form erhalten. Röntgenographische Strukturbestimmung wurde an Einkristallen durchgeführt. I und II zeigen Isotypie, Pn3 (Nr. 201, sec. setting) Z = 4, I: a = 12,772(3) Å, II: a = 13,350(2) Å. III weist eigenen Strukturtyp auf: Pbca (Nr. 61), Z = 4, a = 16,058(3) Å, b = 10,643(2) Å, c = 16,963(3) Å. In I—III liegen trigonal planare CuX3-Gruppen vor. Bindungsverhältnisse und Meßergebnisse der Ionenleitfähigkeit werden diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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