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  • 1
    ISSN: 1434-0879
    Keywords: Urolithiasis ; calcium oxalate ; Crystal growth ; Ion-selective electrode ; Automated kinetic measurement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Monitoring of crystallization of calcium salts with ion-selective electrodes has turned out to be a very sensitive method. The difficulties of handling these electrodes in native whole urine and other biological fluids have been eliminated by new calcium analyzers, which clean and calibrate the electrodes after each measurement. To study crystallization kinetics, repeated calcium ion measurements have to be performed at regular intervals. For this purpose we have developed a special sampler and software. The sampler brings a thermostat-controlled crystallization chamber to the analyzer at preselected intervals. The computer directs and coordinates the sampler and the analyzer, stores the received results and prints out growth curves. Furthermore it calculates the half-time (h) and the maximum decrease of ionic calcium at infinite incubation time (ΔCa ∞ 2+ ). Both values are shown to characterize the growth of calcium oxalate monohydrate in urine. Results are obtained within 40 min.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0794
    Keywords: C/1995 O1 Hale-Bopp ; comets ; infrared spectroscopy ; ISO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H2O, CO2 and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H2O:CO2:CO at 3 AU pre-perihelion. H2O is observed at high spectral resolution in the ν3 group of bands around 2.7 μm and the ν2 group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν3 band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H2O, CO2 and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 1028,3.5 × 1028 and ≈1.5 × 1029 s-1, respectively. This corresponds to H2O:CO2:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO2 rather than by H2O.
    Type of Medium: Electronic Resource
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