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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 16752-16756 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 33 (2000), S. 664-668 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: We report the results of a SANS study into the structure of the adsorbed layers formed at the interface in a dilute perfluorodecalinin-water emulsion by five short chain diblock copolymers of oxyethylene (OE) and oxybutylene (OB). The results are discussed in the context of the Marques-Joanny-Leibler scaling description of block copolymer adsorption from selective solvents. The volume fraction profiles are best described by parabolic and, to a lesser extent, Gaussian functional forms. On increasing the temperature the buoy segments of one copolymer were found to contract toward the surface, giving rise to profiles that were more block-like in accordance with the mean-field predictions of Wijmans and Zhulina.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chester : International Union of Crystallography (IUCr)
    Journal of synchrotron radiation 6 (1999), S. 682-684 
    ISSN: 1600-5775
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chester : International Union of Crystallography (IUCr)
    Journal of synchrotron radiation 8 (2001), S. 191-195 
    ISSN: 1600-5775
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Lanthanide and actinide intermetallic compounds display a wide range of correlated-electron behavior, including ferromagnetism, antiferromagnetism, nonmagnetic (Kondo) ground states, and so-called `non-Fermi liquid' (NFL) behavior. The interaction between f electrons and the conduction band is a dominant factor in determining the ground state of a given system. However, lattice disorder can create a distribution of interactions, generating unusual physical properties. These properties may include NFL behavior in many materials. In addition, lattice disorder can cause deviations from standard Kondo behavior that is less severe than NFL behavior. A review of the lattice disorder mechanism within a tight-binding model is presented, along with measurements of the YbBCu4 and UPdxCu5−x systems, demonstrating the applicability of the model. These measurements indicate that while the YbBCu4 system appears to be well ordered, both site interchange and continuous bond-length disorder occur in the UPdxCu5−x series. Nevertheless, the measured bond-length disorder in UPdCu4 does not appear to be enough to explain the NFL properties simply with the Kondo disorder model.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chester : International Union of Crystallography (IUCr)
    Journal of synchrotron radiation 6 (1999), S. 543-545 
    ISSN: 1600-5775
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1432-0495
    Keywords: Key words Aquifer properties ; Mining ; Subsidence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Subsidence due to longwall underground coal mining changes the hydraulic properties, heads, yields, and in some cases the groundwater chemistry of overlying bedrock aquifers. A 7-year study of a sandstone aquifer overlying an active longwall mine in Illinois has supported a comprehensive model of these impacts. Subsidence caused increases in permeability and storativity over the longwall panel. These changes initially caused a major decline in water levels in the sandstone, but the aquifer recovered slightly within a few months and fully within several years after mining. The enhanced hydraulic properties combined with potentiometric recovery resulted in a zone of greater well yield. However, at sites with very poor transmissivity and inadequate recharge pathways, recovery may not occur. Also, at the study site, the physical enhancement was accompanied by a deterioration in groundwater quality from slightly brackish, sodium bicarbonate water to more brackish water with increased sulfate levels.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Apoptosis 1 (1996), S. 191-200 
    ISSN: 1573-675X
    Keywords: Apoptosis ; EGF-receptor ; epithelium ; intestine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The EGF-like family of growth factors are known to be involved in the control of the intestinal epithelium. The intracellular events are mediated by the EGF receptor (EGFr), a transmembrane glycoprotein which is overexpressed in many malignancies and also in many radiosensitive cell types. The precise mode of action of the receptor in controlling proliferation and whether the factor is also involved in controlling apoptosis in this tissue is not clear. Using polyclonal antibodies raised against a cytoplasmic region of the receptor distant to the phosphorylation site and one raised against the peptide sequence DVVDADEYLIPQ, which is present in the cytoplasmic tail phosphorylation site of the EGFr, we have examined the immunostaining in normal and irradiated murine intestine. The former antibody labelled the basolateral membranes of the epithelial cells in the proliferative zones of both the small intestine and colon, in both control and irradiated tissue. The latter antibody however, strongly labelled the Goblet cells and the microvilli of the enterocyte apical membrane in control tissue. Following irradiation\ the apical labelling redistributed and was localized in the apical cytoplasm and in a paranuclear region. Furthermore, strong labelling was now seen in many of the apoptotic cells of the small intestinal epithelium. The greatly differing results with the two antibodies indicates that interpretation of such immunostaining must be viewed with caution and may relate to the availability of each particular epitope. These results also suggest that antibodies to DVVDADEYLIPQ may be a useful marker of apoptotic calls and could imply a correlation between high levels of epitope availability, the radiosensitive (frequently p53 expressing) cells of the crypt epithelium and the induction of apoptosis.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Hydrogeology journal 7 (1999), S. 561-575 
    ISSN: 1435-0157
    Keywords: Key words coalfield hydrogeology ; subsidence ; mining ; hydrochemistry ; USA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Résumé Les aquifères situés au-dessus de mines de charbon et soumis à de forts pompages ne sont pas affectés par le drainage minier, mais peuvent montrer des modifications du chimisme des eaux souterraines dues à celles de l'écoulement souterrain provoquées par l'abaissement piézométrique au niveau de la mine. Dans deux sites miniers en activité de l'Illinois (États-Unis), des aquifères de moraines glaciaires n'ont pas, de façon générale, été affectés par l'exploitation minière; mais la géochimie des aquifères du substratum s'est modifiée lors de la remontée de la nappe, après arrêt de l'exploitation. Sur le site de Jefferson, où l'exploitation était pratiquée sur un large front, des eaux saumâtres, fortement sulfatées, existant dans les marnes du sommet du substratum, ont présenté très brièvement de plus faibles minéralisations après l'arrêt de la mine, du fait de l'accroissement de la recharge à partir de l'aquifère sus-jacent, tandis que la minéralisation et les sulfates ont augmenté dans les eaux bicarbonatées sodiques des grès sous-jacents, à cause de la drainance des marnes et de venues latérales d'eaux dans les grès. Sur le site de Saline, les grès contenaient des eaux de minéralisation variant de saumâtre à faciès chloruré sodique à douce à faciès bicarbonaté sodique. La remontée de la nappe après l'arrêt de l'exploitation a été minimale et les eaux ont subi des changements de qualité mineurs. L'exploitation minière sur un large front de taille affecte le chimisme des eaux à cause de la fracturation liée à l'effondrement, qui favorise l'augmentation de la drainance à l'aval à partir des formations sus-jacentes, et à cause de la dépression piézométrique temporaire et de la remontée consécutive, lorsque les eaux des zones voisines de l'aquifère rechargent la zone affectée au-dessus et à côté de la mine.
    Notes: Abstract  Aquifers above high-extraction underground coal mines are not affected by mine drainage, but they may still exhibit changes in groundwater chemistry due to alterations in groundwater flow induced by mine subsidence. At two active longwall mine sites in Illinois, USA, glacial-drift aquifers were largely unaffected by mining, but the geochemistry of the bedrock aquifers changed during the post-mining water-level recovery. At the Jefferson site, brackish, high-sulfate water present in the upper bedrock shale briefly had lower values of total dissolved solids (TDS) after mining due to increased recharge from the overlying drift, whereas TDS and sulfate increased in the sodium-bicarbonate water present in the underlying sandstone due to downward leakage from the shale and lateral inflow of water through the sandstone. At the Saline site, sandstones contained water ranging from brackish sodium-chloride to fresh sodium-bicarbonate type. Post-mining recovery of the potentiometric levels was minimal, and the water had minor quality changes. Longwall mining affects geochemistry due to subsidence-related fracturing, which increases downward leakage from overlying units, and due to the temporary potentiometric depression and subsequent recovery, whereby water from surrounding areas of the aquifer recharges the affected zone above and adjacent to the mine.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1572-9605
    Keywords: X-ray-absorption fine-structure (XAFS) ; “colossal” magnetoresistance (CMR) ; Jahn–Teller polarons ; La1−x A x MnO3 ; La1−y MnO3+δ
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We review the distortions of the MnO6 octahedra reduced by magnetization in hole-doped lanthanum manganese perovskites. The systems we consider include the “colossal” magnetoresistance (CMR) samples La1−x Ca x MnO3 (x=0.21, 0.25, 0.30), La0.67Ba0.33MnO3, and a poorer quality La0.67Pb0.33MnO3 sample. We also report preliminary work on three samples of oxygen-doped LaMnO3+δ and a lanthanum-deficient La0.9MnO3 sample. We find the same exponential relationship between the removal of the distortion and the sample magnetization in the Ba- and Pb-doped CMR samples as was found previously for the Ca-doped samples. The MnO6 distortion in the oxygen-doped materials is found to slightly reduce below the magnetic transition, although much less so than in the CMR samples. Above T c, the antiferromagnetic LaMnO3.006 sample shows a softer temperature dependence of the Mn–O bond length distribution broadening. Surprisingly, even this sample shows deviations from thermal (Debye) behavior near T N, possibly due to FM coupling within MnO planes.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Crystallization in concentrated aqueous solutions of the alcohol ethoxylate diblock copolymers C11E40, C15E39 and C17E40 (where C = methylene or methyl and E = oxyethylene) has been investigated using small-angle X-ray scattering (SAXS), wide-angle X-ray scattering (WAXS) and rheology. It is shown that the gel phase formed in these materials has body-centred cubic (bcc) symmetry, and that the bcc structure can be macroscopically oriented by large amplitude oscillatory shear. At concentrations above about 55 wt.-% copolymer, crystallization of the poly(oxyethylene) block occurs at low temperatures, and the effect of crystallization from the oriented bcc structure of a 70 wt.-% solution is examined using SAXS/WAXS. Crystallization induces a second phase separation, i.e. the semicrystalline lamellar structure resulting from poly(oxyethylene)-block crystallization is incommensurate with the oriented bcc structure, with which it coexists at low temperatures. However, crystallization produces an unoriented lamellar structure. WAXS indicates that the poly(oxyethylene) in the diblock copolymer crystallizes in its usual (helical) form.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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