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  • 2000-2004  (1)
  • 1995-1999  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of polymers and the environment 3 (1995), S. 161-167 
    ISSN: 1572-8900
    Keywords: Corn starch ; polyvinyl alcohol ; biodegradable blends ; rheology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The rheological behavior of biodegradable blends of starch and poly(vinyl alcohol) (PVOH) was measured as a function of temperature, shear rate, and moisture content using a capillary rheometer. An excellent correlation was found with a rheological model which was used as a means to characterize the influence of starch/PVOH content as well as a qualification of the viscosity for simulation studies. This model consisted of a power law dependence on shear rate, an Arrhenius dependence on temperature, and an exponential dependence on moisture.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 11 (2000), S. 227-233 
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract PCL/PEO copolymers with different compositions were obtained from ring opening polymerization of ε-caprolactone in the presence of ethylene oxide and characterized by various analytical techniques. Data collected from DSC and X-ray diffractometry suggested that the copolymer chains possess a blocky structure, leading to both PCL and PEO-type crystalline structures. Hydrolytic degradation of these copolymers was carried out in a pH=10.6 carbonate buffer solution at 37 °C. Comparison was made with a PCL homopolymer and a PCL/PEG blend which had the same gross composition as one of the copolymers. The results showed that the presence of PEO sequences considerably enhanced the hydrophilicity of the copolymers as compared with PCL homopolymer. Nevertheless, the degradability of PCL chains was not enhanced due to the phase separation between the two components. These materials should be of great interest for biomedical uses such as matrices for sustained drug delivery because of the presence of both hydrophilic and hydrophobic microdomains. ©2000 Kluwer Academic Publishers
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 755-762 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influences of processing variables on the mechanical properties of general grade poly-propylene prepared by oscillating packing injection molding under low pressure were reported. The density as a function of oscillating holding pressure was measured using density gradient columns. The existence of spherulites and shear-induced shish-kebab crystals was confirmed from DSC measurements. The texture of self-reinforced polypropylene was investigated using an X-ray diffractometer and an X-ray flat film camera. Investigations indicate that the mechanical properties of polypropylene can be greatly enhanced using oscillating packing injection molding. The Young's modulus and tensile strength have been enhanced from original 1.4 GPa, 31.0 MPa to 3.0 GPa, 57.8 MPa, respectively. The improvement in mechanical properties is mainly ascribed to perfect spherulites, the existence of shear-induced shish-kebab crystals, and the orientation of molecular chains. © 1996 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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