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  • 1
    ISSN: 1572-9605
    Keywords: texture YBCO ; BaZrO3 ; ultrafine particles ; pushing effect ; seeding effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We prepared precursors with fine BaZrO3 inclusions for melt-texture growth of high-temperature superconductors with nominal composition of Y1.5Ba2Cu3O y + x BaZrO3 (x = 0, 0.04, 0.08, and 0.1), by the process of liquid-phase powder melt-texture growth (LPMG). We then investigated the effects of the precursors on the texture growth and the microstructure of composite YBa2Cu3O7-δ/Y2BaCuO5 (YBCO). The BaZrO3 particles were about 100 nm in size in the textured YBa2Cu3O7-δ (Y123), observed by the scanning electron microscopy (SEM). Owing to the pushing effects of growing fronts, fine particles were pushed out of and thus gathered in front of the growing fronts or between Y123 grains. The gathered particles in turn blocked the further growth of the Y123 grains. However, BaZrO3 particles seeded Y123 grains, giving rise to multigrain growths. These negative effects of BaZrO3 fine particles exclude themselves as effective flux pinning centers in the textured YBCO.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 23 (1994), S. 406-416 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This study shows that fast atom bombardment (FAB) in combination with collisional activation and tandem mass spectrometric techniques is useful for the characterization of, and the differentiation between, O-diglycosyl, O-C- diglycosyl, and di-C-glycosyl flavonoids. A quick differentiation between the three types of glycosyl flavonoids is possible by simply examining FAB mass spectra. Low-energy product ion spectra of [M + H] + ions have been used for determining the carbohydrate sequence in O-diglycosyl flavonoids and characterizing the terminal mono-saccharide in O-C-diglycosyl flavonoids. The data obtained for per-O- deuterated precursor ion species of O-diglycosyl flavonoids indicate that O-linked hydrogen atoms are involved in the formation of Yn + ions. High-energy product ion spectra of [M + H] + ions enable further characterization and differentiation of isomeric di-6,8-C-glycosides.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 21 (1992), S. 213-221 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The present study deals with the use of liquid secondary ion mass spectrometry in combination with collisionally activated dissociation and linked scanning at constant B/E for differentiation and structural analysis of 6-C- and 8-C-glycosidic flavonoids in the positive ion mode. Flavonoids of mono-C-glycosidic nature were investigated. Special emphasis is given to the rationalization of fragment ions which allow differentiation between isomers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 21 (1992), S. 408-410 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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