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  • 1
    Electronic Resource
    Electronic Resource
    The perovskite structure – a review of its role in ceramic science and technology (2000)
    Springer
    Materials research innovations 4 (2000), S. 3-26 
    Details
    ISSN: 1433-075X
    Keywords: Keywords Perovskite ; Crystal-chemistry ; Tolerance factor ; Ferroics ; Electro-ceramics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Starting with the history of the fundamental science of the relation of structure to composition delineated completely by Goldschmidt, we use the perovskite structure to illustrate the enormous power of crystal chemistry-based intelligent synthesis in creating new materials. The perovskite structure is shown to be the single most versatile ceramic host. By appropriate changes in composition one can modify the most significant electroceramic dielectric (BaTiO3 and its relatives) phase in industry, into metallic conductors, superconductors or the highest pressure phases in the earth. After an historical introduction of the science, detailed treatment of the applications is confined to the most recent research on novel uses in piezoelectric, ferroelectric and related applications.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s100190000062
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    The microstructure and properties of framework zirconium phosphates based nanocomposites – catalysts of alkane isomerization (2000)
    Springer
    Materials research innovations 3 (2000), S. 276-285 
    Details
    ISSN: 1433-075X
    Keywords: Key words Nanocomposites ; Framework zirconium phosphates ; Supported nanoparticles of WO3 ; MoO3 and Pt ; Catalysis of pentane and hexane isomerization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Nanocomposites based upon framework zirconium phosphates with supported WO3, MoO3 and Pt nanoparticles were synthesized via the incipient wetness impregnation of high-surface-area mesoporous phosphate samples with water solutions of corresponding salts followed by drying and calcination. The structure and surface properties of nanocomposites were studied by using combination of structural and spectral methods. Due to a strong interaction between supports and supported species, the structure of the latter differs considerably from that of the bulk phases. Surface acid centers typical for zirconium phosphates disappear suggesting their participation in bonding nanoparticles of promoters. Instead, new types of strong acid sites associated with tungsten oxide clusters emerge. The effect of these promoters on performance of zirconium phosphates in the reaction of pentane and hexane isomerization is considered.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s100190000051
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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