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  • 1
    Book
    Book
    Chichester u.a. :Wiley,
    Title: Essentials of computational chemistry : Theories and models
    Author: Cramer, C.
    Publisher: Chichester u.a. :Wiley,
    Year of publication: 2002
    ISBN: 0-471-48552-7
    Type of Medium: Book
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  • 2
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have built an end station for x-ray magnetic circular dichroism (XMCD) measurements on proteins and paramagnetic compounds. Our current setup reaches a base temperature of 2.6 K and magnetic fields up to 6 T and is operated at beamline 4.02 of the Advanced Light Source. In this article we discuss magnetic field and low temperature requirements needed to perform XMCD experiments on magnetically saturated samples. For a typical 3d transition metal paramagnetic system we find that fields above 4 T at a temperature of 2.6 K saturate the magnetization of the sample to more than 80%. We discuss principal considerations for a setup operated at low temperatures on a synchrotron and show that infrared heat shielding is unavoidable to obtain the base temperature at the sample. We show first experimental results from the vanadium (IV) compound VOSO4X[H2O]. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6911-6913 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have constructed a series of microstrips for transmission of microwaves. These microstrips incorporate ferromagnetic and dielectric layers and therefore absorb microwave energy at the ferromagnetic resonance (FMR) frequency. The absorption notch in transmission can be tuned to various frequencies by varying an external applied magnetic field. For our devices, which incorporate Fe as the ferromagnetic material, the resultant FMR frequencies range from 10–20 GHz for applied fields up to only 1000 Oe. This frequency range is substantially higher than those found in devices utilizing a dielectric ferrimagnet such as YIG. We constructed devices using monocrystalline Fe films grown in a molecular beam epitaxy system. Our devices are of different construction than other Fe dielectric microstrips and show much improvement in terms of notch width and depth. We observed maximum attenuation on the order of 100 dB/cm, much larger than previously reported values of 4 dB/cm. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 7 (2000), S. 391-402 
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Recent one-dimensional particle-in-cell simulations of a cylindrical postcathode direct current magnetron discharge have shown a transition from the usual positive space charge mode, dominated by a strong cathode fall, to a higher impedance negative space charge mode, characterized by a broad anode fall, as either the pressure is decreased or the magnetic field is increased. Such behavior is consistent with a steady decrease in the cross-field electron transport coefficients as calculated from classical fluid theory. However, experimental measurements of the distribution of electric potential between the electrodes do not exhibit any systematic variation with changes in magnetic field or pressure. This suggests that anomalous transport mechanisms increase the electron transport above the level predicted by classical transport theory, so maintaining the positive space charge mode at low pressures. It is shown using a fluid model that electrostatic oscillations with ω(approximately-greater-than)νi, where νi is the ion-neutral collision frequency, propagating in the E×B direction are unstable with growth rates comparable to the charged particle transit times. Such oscillations, which cannot be modeled in a one-dimensional particle-in-cell model, may contribute to the anomalous transport observed in experiments. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd.
    Journal of management studies 40 (2003), S. 0 
    ISSN: 1467-6486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: The debate between adaptation and inertia hinges on whether theorists believe that organizations can effect purposive organizational change in which the realized structures match the planned structures. To date, research on organizational change has yielded few insights into the conditions under which such change occurs. This longitudinal case study of a re-engineering programme at a medium-sized bank examined the conditions under which elements of the planned structure were faithfully implemented. Elaborating a model of change fidelity, this paper argues that the features of the design elements themselves, attributes of the change process, and general contextual factors affect the likelihood that planned changes will occur.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1095-9270
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Archaeology
    Notes: Since all long-distance trade in the Roman world travelled by water, Roman harbour design and construction have special importance. Harbour excavation must be supplemented by analysis of the components of the hydraulic concrete, structural analysis of the cementing materials, and consideration of the design of the wooden formwork. The authors have begun collecting large cores from concrete blocks at Roman harbours and other maritime structures, analysing the materials used, the method of placement, and the structural characteristics of the resulting concrete. These data have provided new information on the engineering properties of Roman concrete, the process of funding and execution, and the trade in the volcanic ash which was the crucial component of hydraulic concrete.© 2004 The Nautical Archaeology Society
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Biomedical Engineering 6 (2004), S. 497-525 
    ISSN: 1523-9829
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Technology , Medicine
    Notes: Robotic devices are helping shed light on human motor control in health and injury. By using robots to apply novel force fields to the arm, investigators are gaining insight into how the nervous system models its external dynamic environment. The nervous system builds internal models gradually by experience and uses them in combination with impedance and feedback control strategies. Internal models are robust to environmental and neural noise, generalized across space, implemented in multiple brain regions, and developed in childhood. Robots are also being used to assist in repetitive movement practice following neurologic injury, providing insight into movement recovery. Robots can haptically assess sensorimotor performance, administer training, quantify amount of training, and improve motor recovery. In addition to providing insight into motor control, robotic paradigms may eventually enhance motor learning and rehabilitation beyond the levels possible with conventional training techniques.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 113 (2000), S. 3930-3930 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: The possible responses of ecosystem processes to rising atmospheric CO2 concentration and climate change are illustrated using six dynamic global vegetation models that explicitly represent the interactions of ecosystem carbon and water exchanges with vegetation dynamics. The models are driven by the IPCC IS92a scenario of rising CO2 (Wigley et al. 1991), and by climate changes resulting from effective CO2 concentrations corresponding to IS92a, simulated by the coupled ocean atmosphere model HadCM2-SUL. Simulations with changing CO2 alone show a widely distributed terrestrial carbon sink of 1.4–3.8 Pg C y−1 during the 1990s, rising to 3.7–8.6 Pg C y−1 a century later. Simulations including climate change show a reduced sink both today (0.6–3.0 Pg C y−1) and a century later (0.3–6.6 Pg C y−1) as a result of the impacts of climate change on NEP of tropical and southern hemisphere ecosystems. In all models, the rate of increase of NEP begins to level off around 2030 as a consequence of the ‘diminishing return’ of physiological CO2 effects at high CO2 concentrations. Four out of the six models show a further, climate-induced decline in NEP resulting from increased heterotrophic respiration and declining tropical NPP after 2050. Changes in vegetation structure influence the magnitude and spatial pattern of the carbon sink and, in combination with changing climate, also freshwater availability (runoff). It is shown that these changes, once set in motion, would continue to evolve for at least a century even if atmospheric CO2 concentration and climate could be instantaneously stabilized. The results should be considered illustrative in the sense that the choice of CO2 concentration scenario was arbitrary and only one climate model scenario was used. However, the results serve to indicate a range of possible biospheric responses to CO2 and climate change. They reveal major uncertainties about the response of NEP to climate change resulting, primarily, from differences in the way that modelled global NPP responds to a changing climate. The simulations illustrate, however, that the magnitude of possible biospheric influences on the carbon balance requires that this factor is taken into account for future scenarios of atmospheric CO2 and climate change.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: We assess the role of changing natural (volcanic, aerosol, insolation) and anthropogenic (CO2 emissions, land cover) forcings on the global climate system over the last 150 years using an earth system model of intermediate complexity, CLIMBER-2. We apply several datasets of historical land-use reconstructions: the cropland dataset by Ramankutty & Foley (1999) (R&F), the HYDE land cover dataset of Klein Goldewijk (2001), and the land-use emissions data from Houghton & Hackler (2002). Comparison between the simulated and observed temporal evolution of atmospheric CO2 and δ13CO2 are used to evaluate these datasets. To check model uncertainty, CLIMBER-2 was coupled to the more complex Lund–Potsdam–Jena (LPJ) dynamic global vegetation model.In simulation with R&F dataset, biogeophysical mechanisms due to land cover changes tend to decrease global air temperature by 0.26°C, while biogeochemical mechanisms act to warm the climate by 0.18°C. The net effect on climate is negligible on a global scale, but pronounced over the land in the temperate and high northern latitudes where a cooling due to an increase in land surface albedo offsets the warming due to land-use CO2 emissions.Land cover changes led to estimated increases in atmospheric CO2 of between 22 and 43 ppmv. Over the entire period 1800–2000, simulated δ13CO2 with HYDE compares most favourably with ice core during 1850–1950 and Cape Grim data, indicating preference of earlier land clearance in HYDE over R&F. In relative terms, land cover forcing corresponds to 25–49% of the observed growth in atmospheric CO2. This contribution declined from 36–60% during 1850–1960 to 4–35% during 1960–2000. CLIMBER-2-LPJ simulates the land cover contribution to atmospheric CO2 growth to decrease from 68% during 1900–1960 to 12% in the 1980s. Overall, our simulations show a decline in the relative role of land cover changes for atmospheric CO2 increase during the last 150 years.
    Type of Medium: Electronic Resource
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