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  • 2000-2004  (3)
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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The relation between electrical and structural properties of indium tin oxide (ITO) films prepared by pulsed laser deposition with and without in situ laser irradiation is examined. The residual stresses of the films were estimated from x-ray diffraction patterns measured by grazing-incidence asymmetric Bragg and grazing-incidence x-ray diffraction geometries. For the films prepared without in situ irradiation, the residual stress depended on oxygen pressure (PO2) during deposition and had minimum around PO2 of 1.3 Pa, which coincided with the optimum PO2 for growing the lowest resistivity films. The resistivity was only slightly improved with an increase of substrate temperature (Ts) because a large residual stress was introduced. In contrast, the ITO films prepared with in situ laser irradiation showed very low resistivity (ρ〈10−4 Ω cm) which can be attributed to the high crystallinity and low residual stress. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The structural parameters of orthorhombic and tetragonal phases (space group P/mmm and P4/mmm) of A-site deficient La0.683(Ti0.95Al0.05)O3 perovskite have been refined by Rietveld analysis through the X-ray powder diffraction patterns measured in the temperature range from 15° to 500°C. With an increase in temperature the unit-cell parameters a, b, and c increased, while the b/a ratio decreased and became unity between 200° and 400°C. No significant changes were observed for atomic coordinates throughout the temperature studied. These results strongly suggest that the phase transition is induced by lattice distortion.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The structure and electrical properties of an A-site-deficient perovskite compound found in the La2/3TiO3-La1/3NbO3 system were investigated. The composition of the perovskite compound seemed to be very close to La0.633(Ti0.90Nb0.10)O3. X-ray diffraction analysis revealed a superstructure with a doubled c-axis parameter, resulting from an ordered arrangement of the A-site cation vacancies. Impedance measurements on the compound showed that La0.633(Ti0.90Nb0.10)O3 had high ionic conductivity at relatively low temperature (〈770 K) and increased electronic conduction at high temperature (〉770 K). The bulk ionic conductivity was comparable with that of La0.683(Ti0.95Al0.05)O3, which has the highest ionic conductivity among the La-(Ti,Al)-O perovskite compounds.
    Type of Medium: Electronic Resource
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