ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The main process of the electron impact induced water elimination of the title compounds takes a reaction course comprising several individual steps. A characteristic neighbouring group participation of the carbonyl function is involved, onto which a hydrogen is transferred in a first rate-determining reaction step. This rearranged hydrogen is finally lost together with the hydroxyl group. The reaction of N-(2′-hydroxyethyl)piperidone follows what seems to be a [1,1] elimination whereas the H2O elimination from N-(3′-hydroxypropyl)piperidone represents a formal [1,2] elimination.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210180808
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