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  • 1995-1999  (3)
  • 1960-1964  (1)
  • Inorganic Chemistry  (2)
  • Darcian model  (1)
  • Isotope effect  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 8 (1995), S. 9-10 
    ISSN: 1572-9605
    Keywords: Isotope effect ; superconductivity ; fullerenes ; oxide superconductors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The role of pair breaking effects on the isotope effect coefficient is investigated using the generalized Abrikosov and Gorkov theory of superconductors. It is found that the pair breaking effects enhance the isotope effect coefficient. This provides a plausible explanation for the enhancement of the isotope effect coefficient as a function of impurity concentration in yttrium-, europium-, and lanthanum-based high-T c superconductors. It may also explain the very large value of the isotope effect coefficient in Rb3C60 superconductors provided some intrinsic disorder is assumed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 1093-1098 
    ISSN: 0009-2940
    Keywords: Indium tris(thiobenzoate) ; Triethylammonium tetrakis(thiobenzoato)indate ; Tin, butyl-, tris(thiobenzoate) ; Tin, dichloro-, bis(thiobenzoate) ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Indium(III) and tin(IV) thiocarboxylates were prepared and characterized on the basis of their IR, 13C- and 19Sn-NMR data. Indium tris(thiobenzoate) (1) decomposes into a sulfido complex In (S)[S(O)CPh] (2a). The corresponding tris(thioacetate) In[S(O)CMe]3 is thermally too unstable to be isolated. The anionic tetrakis complex [Et3NH]{In[S(O)CPh]4} (3) was characterized by X-ray crystallography which revealed a distorted tetrahedral coordination at the In atom. X-ray diffraction analysis of the complexes BuSn[S(O)CPh]3 (4) and Cl2Sn[S(O)CPh]2 (7) showed distorted tetrahedral and cis-octahedral structures, respectively.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 332 (1964), S. 103-112 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung und Eigenschaften von Additionsverbindungen des SnCl4 mit N, N-Dimethylformamid, Acetamid, Acetanilid und Benzamid werden mitgeteilt. Neben der Analyse zeigen auch Donator-Acceptor-Titrationen in Dichloräthan die allgemeine Formel SnCl4 · 2 Amid. Leitfähigkeitsmessungen in Nitromethan und Molekulargewichtsbestimmungen lassen auf das Vorliegen von monomeren Additionsverbindungen schließen. Aus den IR-Spektren geht an Hand einer Erniedrigung der (C—O)- und einer Erhöhung der (C—N)-Valenzschwingung eine Bindung der organischen Liganden an das Zinn über Sauerstoff hervor. Die relativen Basenstärken nehmen in der Reihe Dimethylformamid, Benzamid, Acetanilid, Acetamid ab.
    Notes: The molecular addition compounds of tin (iv) chloride with N, N-dimethyl formamide, acetamide, acetanilide, and benzamide have been prepared. They are of the type SnCl4 · 2 amide. This composition type has been confirmed by indicator titrations of stannic chloride against amides in dichloroethane. Conductivity measurements in nitromethane and molecular weight determinations show that they are true molecular addition compounds being monomeric.The infrared spectra of the adducts show that there are metal-to-oxygen bonds in all these compounds as is evidenced by a negative shift of the carbonyl stretching frequency and a positive shift of the C—N stretching frequency. The relative donor ability of the amides towards stannic chloride has been found to be: dimethyl formamide 〉 benzamide 〉 acetanilide 〉 acetamide.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 28 (1998), S. 633-661 
    ISSN: 0271-2091
    Keywords: free convection ; porous enclosure ; Darcian model ; wavy surface ; finite element method ; numerical study ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The coupled streamfuction-temperature equations governing the Darcian flow and convection process in a fluid-saturated porous enclosure with an isothermal sinusoidal bottom sun face, has been numerically analyzed using a finite element method (FEM). No restrictions have been imposed on the geometrical non-linearity arising from the parameters like wave amplitude (a), number of waves per unit length (N), wave phase (Φ), aspect ratio (A) and also on the flow driving parameter Rayleigh number (Ra). The numerical simulations for varying values of Ra bring about interesting flow features, like the transformation of a unicellular flow to a multicellular flow. Both with increasing amplitude and increasing number of waves per unit length, owing to the shift in the separation and reattachment points, a row-column pattern of multicellular flow transforms to a simple row of multicellular flow. A cycle of n celluar and n+1 cellular flows, with the flow in adjacent cells in the opposite direction, periodically manifest with phase varying between 0 and 360°. The global heat transfer into the system has been found to decrease with increasing amplitude and increasing number of waves per unit length. Only marginal changes in the global heat flux are observed, either with increasing Ra or varying Φ. Effectively, sinusoidal bottom surface undulations of the isothermal wall of a porous enclosure reduces the heat transfer into the system. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
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