Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1995-1999  (2)
  • 1880-1889
  • Gas chromatography  (1)
  • Key words Car accident • Fracture of the foot • Injury mechanism • Long-term outcome  (1)
  • 1
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Molecular modelling ; Molecular mechanics calculations ; Permethylated α-, β- and γ-cyclodextrins ; Interaction mechanism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The capillary gas chromatographic retention behavior of α-pinene and tricyclene has been investigated on stationary phases of different polarities. On all but one of the columns employed, tricyclene eluted before α-pinene; only permethylated β-cyclodextrins dissolved in moderately polar polisiloxanes gave a reversed elution order. The intermolecular interactions which caused the unexpected retention behavior were investigated in detail, applying methods of computer simulation. To achieve this, we have developed a calculation algorithm on the basis of molecular mechanical optimizations and programmed it in a macro. This makes it possible to systematically investigate a given configuration space in which all the possible interactions can take place. It was shown that permethylated β-cyclodextrin as host molecule for both guest molecules offers an optimum cavity size. As a result the number of energetically favorable contacts between host and guest molecules as well as the strength of the interactions in this stationary phase were larger. As a consequence the elution order, normally only influenced by the vapor pressure of the compounds at a given temperature, was changed. Nonspecific interactions played an especially important role for these kinds of substances.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 1433-044X
    Keywords: Key words Car accident • Fracture of the foot • Injury mechanism • Long-term outcome ; Schlüsselwörter PKW-Unfall • Fußfraktur • Verletzungsmechanismus • Langzeitfolgen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Description / Table of Contents: Zusammenfassung Bei 6378 Verkehrsunfällen mit 8931 Verletzten zwischen 1973 und 1989 im Großraum Hannover wurden 3267 PKW-Insassen mit Frakturen registriert. Davon hatten 148 (4,5 %) Personen Frakturen im Fußbereich erlitten. Die Unfalldaten wurden in Hinblick auf Verletzungsentstehung, -art und -ausmaß ausgewertet und die Verletzungsfolgen anhand von Langzeituntersuchungen evaluiert. Bei der Entstehung der Fußfrakturen spielte die Deformierung des Fußraums die wesentliche Rolle. Fahrer und Beifahrer erlitten ähnlich schwere Verletzungen. Bei den 286 Frakturen war der Vorfuß am häufigsten betroffen (45 %), gefolgt von OSG (35 %), Mittelfuß (11 %) und Rückfuß (6 %). Der Anteil der offenen Frakturen betrug 5 %. Die Klassifikation erfolgte nach der „Abbreviated Injury Scale“ (AIS) für die untere Extremität. Die Langzeitfolgen wurden anhand der fußverletzungsbedingten Minderung der Erwerbsfähigkeit (MdE) im Verhältnis zur gesamten MdE abgeschätzt. Diese Auswertung ergab, daß die Fußfrakturen vor allem bei erheblichen Begleitverletzungen bei der Primäruntersuchung oft nicht erkannt oder unterschätzt wurden. Die Langzeitfolgen gingen häufig mit einer erheblichen fußverletzungsbedingten Invalidisierung einher.
    Notes: Summary During 1973 and 1989, 6,378 car accidents with 8,931 injured persons were evaluated in the area of Hannover. 3,267 car drivers and passengers sustained fractures overall and 148 (4,5 %) fractures of the foot. A major role in the ethiology of the foot fractures evolves from the deformation of the foot room. Driver and front seat passenger showed similar injuries. Among the 286 single fractures, the forefoot was affected most often (45 %), followed by ankle (38 %), midfoot (11 %) and hindfoot (6 %). 5 % were open fractures. The long term results were estimated upon the limitation of working ability caused by the foot injury in relation to the entire working ability. The evaluation concludes that the foot fractures especially in combination with other injuries were frequently not recognized within the primary examination and therefore underestimated. The long-term outcome leaded to a high degree of impairment due to foot fractures.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...