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  • 1995-1999  (3)
  • fatigue  (2)
  • compatibilizers  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Correlation of fatigue crack propagation in polyethylene pipe specimens of different geometries (1997)
    Springer
    International journal of fracture 84 (1997), S. 159-173 
    Details
    ISSN: 1573-2673
    Keywords: fracture ; fatigue ; polyethylene ; crack propagation ; accelerated failure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Correlation in mechanisms and kinetics of step-wise fatigue crack propagation in polyethylene pipe specimens of different geometries is studied experimentally. It is shown that crack propagation in a non-standard specimen cut from a real pipe and conserving the pipe geometry can be effectively simulated using a standard compact tension specimen. Good correlation in both kinetics of step-wise crack propagation and fractography between the specimens is achieved if experimental conditions are chosen to assure equal values of (a) stress intensity factor and (b) stress intensity factor gradient at the initial notch tips. These results extend previous technique of fatigue accelerating slow crack growth used to predict lifetime of polyethylene pipes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1007354600584
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Block copolymers as compatibilizers for blends of linear low density polyethylene and polystyrene (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 667-683 
    Details
    ISSN: 0887-6266
    Keywords: blend modulus ; compatibilizers ; polyethylene/polystyrene blends ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Compatibilization of blends of linear low-density polyethylene (LLDPE) and polystyrene (PS) with block copolymers of styrene (S) and butadiene (B) or hydrogenated butadiene (EB) has been studied. The morphology of the LLDPE/PS (50/50) composition typically with 5% copolymer was characterized primarily by scanning electron microscopy (SEM). The SEB and SEBS copolymers were effective in reducing the PS domain size, while the SB and SBS copolymers were less effective. The noncrystalline copolymers lowered the tensile modulus of the blend by as much as 50%. Modulus calculations based on a coreshell model, with the rubbery copolymer coating the PS particle, predicted that 50% of the rubbery SEBS copolymer was located at the interface compared to only 5-15% of the SB and SBS copolymers. The modulus of blends compatibilized with crystalline, nonrubbery SEB and SEBS copolymers approached Hashin's upper modulus bound. An interconnected interface model was proposed in which the blocks selectively penetrated the LLDPE and PS phases to provide good adhesion and improved stress and strain transfer between the phases. © 1995 John Wiley & Sons, Inc.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1995.090330416
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    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Stepwise fatigue crack propagation in polyethylene resins of different molecular structure (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2355-2369 
    Details
    ISSN: 0887-6266
    Keywords: fracture ; fatigue ; polyethylene ; molecular weight distribution ; short chain branch content ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Stepwise fatigue crack propagation in a range of polyethylene resins, some of which are candidates for use in pipes for natural gas distribution, was studied. Examination of the effect of molding conditions on fatigue crack propagation in a pipe resin indicated that fast cooling under pressure produced specimens with the same crack resistance as specimens taken from a pipe extruded from this resin. The mechanism of stepwise crack propagation in fatigue was the same as reported previously for creep loading. Observations of the region ahead of the arrested crack revealed a complex damage zone that consisted of a thick membrane at the crack tip followed by a main craze with subsidiary shear crazes that emerged from the crack tip at an angle to the main craze. The effects of molecular parameters, such as molecular weight, comonomer content, and branch distribution, on the kinetics of fatigue crack propagation were examined. Correlation of creep and fatigue crack resistance made it possible to relate fatigue fracture toughness to molecular parameters by invoking concepts of craze fibril stability developed for creep. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2355-2369, 1998
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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