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The Halogenation of Some Benzamides Takes Place Preferentially at the ortho, para Positions (1998)

Dong, Chang-Zhi ; Julia, Marc ; Tang, Jie

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 1689-1696

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ISSN: 1434-193X

Keywords: Aromatic substitution ; Benzamides ; Chlorination ; Bromination ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The orientation of chlorination and bromination of N, N-disubstituted benzamides in aqueous acetic acid is strongly influenced by the nature of the alkyl groups at the nitrogen atom. With large groups, the halogenation takes place fairly selectively at the ortho/para positions.

Type of Medium: Electronic Resource

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