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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water resources management 12 (1998), S. 13-30 
    ISSN: 1573-1650
    Keywords: risk ; reliability ; resiliency ; vulnerability ; drought risk index ; drought damage index ; simulation ; water supply ; reservoir operation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: Abstract In this study, simulation is used to evaluate the performance of the municipal water system in Fukuoka city. In combination with daily simulation model, a kind of risk model incorporating water demand prediction is presented. This model applies five risk indices: reliability, resiliency, vulnerability, drought risk index (DRI) and drought damage index (DDI). They aid in the identification of operation policies for the municipal water system, and the planning and operational policies obtained are aimed at achieving minimum risk for a given scenario of operation. In this paper, the performance risk of the municipal water system is investigated under three alternatives: (1) the existing system operation when available supply from the Chikugo river is decreased; (2) water restrictions for different percentages of reduction are implemented; and (3) available water supply increases when desalination of sea water is implemented. The results obtained show that savings of between 5 and 12% of water consumption from May 1, or increasing of daily desalination of sea water about 30 000 m3 or more, may efficiently decrease the performance risk of the Fukuoka water supply system. Potentials also exist for further increase of reservoir storage by more rational operation. The measure that more attention should be paid to increasing the water supply from stable sources is recommended as well.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fullerenes ; Retention vs NMR spectra ; C18 phases ; Low temperature separations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The temperature effect on the retention of fullerenes in the range 80°C to −70°C in liquid chromatography (LC) has been examined using octadecylsilica stationary phases (ODS). It has been found that the maximum retention temperature lies around −10°C with a highly carbon loaded ODS phase. Solid state CPMAS NMR measurements on the stationary phases indicated that the relaxation time at the 30 ppm methylene signal changes with the temperature and has a minimum relaxation time at the temperature which closely matches the maximum retention temperature observed in chromatography. The interpretation of both NMR spectroscopic and LC chromatographic data are discussed.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1612-1112
    Keywords: Microcolumn liquid chromatography ; Cholesteryl 10-undecenoate bonded phase ; Large polycyclic aromatic hydrocarbons
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention behavior of large polycyclic aromatic hydrocarbons (PAH) in reversed-phase microcolumn liquid chromatography has been found to depend primarily on the inherent planarity of the molecules, the degree of orderliness of the bonded phase, and the concentration of solvent. The planarity recognition capability of cholesteryl 10-undecenoate bonded phase for large PAH is comparable with that of monomeric ODS phases. During solvation, however, the phase characteristics seemed to suggest a fairly rigid structure (an ordered phase), i.e. increased selectivity for non-planar molecules which approaches that of polymeric ODS rather than that of other phases with similarly bulky groups, e.g. naphthylethyl and pyrenylethyl bonded phases.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fullerences ; Alkyl bonded silica phases ; Retention vs. column temperature ; CP-MAS NMR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The temperature-dependency of the separation of fullerenes in liquid chromatography (LC) has been examined using various alkyl bonded stationary phases. It has been found that a maximum retention temperature exists with long alkyl bonded stationary phases, whereas there is no similar effect with the newly synthesized alkyl bonded phases which have two phenyl groups at the base of the bonded phase. The interpretation of the retention behavior of fullerenes in the low temperature region on alkyl bonded stationary phases is discussed using information obtained by CP-MAS solid-state NMR spectroscopy and LC.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1612-1112
    Keywords: Microcolumn liquid chromatography ; Alkyl diphenyl bonded phase ; Molecular shape recognition ; Polycyclic aromatic hydrocarbons
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The basic retention behaviors of polycyclic aromatic hydrocarbons (PAHs) with various novel alkyl diphenyl bonded phases have been examined using microcolumn liquid chromatography The retention behaviors of PAHs with these phases have been compared to those with n-alkyl bonded phases which have the same carbon numbers but methyl side groups instead of phenyl groups. Three different alkyl chain lengths for bothn-alkyl dimenthyl andn-alkyl diphenyl bonded phases such as C4, C8 and C 18 were used in this study. It was found that thesen-alkyl diphenyl phases have a non-planarity recognition capability for small and medium PAHs. It appears that this capability increases as the alkyl chain length of the bonded phases decreases. The short or medium alkyl chain length diphenyl bonded phases retained non-planar solutes better than the planar solutes. This trend is completely opposite to that with dimethyl analogs. This unique retention behavior is believed to be caused by strong molecular-molecular interaction between non-planar solutes and the two phenyl groups in those diphenyl stationary phases.
    Type of Medium: Electronic Resource
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