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  • 1990-1994  (3)
  • 1985-1989  (2)
  • 1955-1959
  • Chemistry  (5)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 2839-2847 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: In Auger electron spectroscopy, the relative sensitivities of elements, which are widely used in quantitative analysis, are primarily obtained by measurement. Nevertheless, it is very tedious to collect all relative elemental sensitivity factors for different primary electron beam energies. In view of this, we have examined methods of deriving the relative sensitivity factor for an arbitrary electron beam energy from one experimental value determined at a set energy. For this calculation, we have to consider the contributions of the ionization cross-section and the electron backscattering factor. Several formulas for the ionization cross-section and the backscattering correction factor have been reported. We have performed experiments to examine their correction accuracy. It was found that when Gryziński's formula is used as the ionization cross-section and Love-Scott's formula as the backscattering correction factor, the difference between calculated sensitivity values and measured values was found to be 〈15% for excitation energies of 〈20 keV.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 15 (1994), S. 327-333 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The results of studies on bending properties of three-layer long fiber polypropylene composites are presented. Thirteen samples with glass fibers of various lengths (i.e., 13, 25, 50 mm and continuous fiber length) in the laminates were prepared by stamping. Bending properties of shorter lengths exhibited a large scatter. On substitution of the middle layer with a continuous glass fiber the scatter was reduced. These results have been explained on the basis of flow models and X-ray shadowgraphs, which showed that both slippage flow and orientation of the glass fiber during stamping are the major phenomena responsible for the scatter.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 15 (1994), S. 393-400 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of die design on the flow characteristics of compression molded three-layer long glass fiber reinforced polypropylene composite, known as “stampable sheet,” was investigated. The flow behavior of each layer was observed by optical and soft X-ray photographs. The fiber flow length into the rib part was measured by an image processing system. The results showed that during compression resin exudation occurred and that this depended on the die's rib width. Thus, the larger the rib width, the lower the amount of resin exuded. Resin exudation was found to occur earlier in a die with zero fillet radius. The fiber flow length into the rib part was enhanced by using a die with a large fillet radius. The results were confirmed by a short-shot molding process. In this process, the stamping operation was stopped short of making a complete part.A finite element method was used to study the flow process. The results agree with the experimental results confirmed by short-shot molding.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 45 (1994), S. 399-412 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A statistical mechanical theory is presented for liquid-crystalline polymer solutions, where the liquid-crystalline polymer is regarded as a wormlike spherocylinder interacting by the hard-core repulsion and a soft (attractive or electrostatic) interaction with other spherocylinders. The theory is based on the following two assumptions: (1) the intramolecular excluded volume effect is not effective and (2) the interaction between pair of spherocylinders can be treated by the “single contact approximation”. These assumptions are relevant to a polymer with a stiff backbone and not very long contour length. The theory is used to predict thermodynamic and spatial properties of isotropic solutions and also isotropic-liquid crystal phase equilibrium behavior. The predicted solution properties and phase behavior are favorably compared with experimental results for some selected stiff-chain liquid-crystalline polymers.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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